Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

Much progress has been made in the development of methods to both create compounds
that contain C− F bonds and to functionalize C− F bonds. As such, C− F bonds are becoming …

Stereo‐and enantioselective cross‐electrophile coupling involving C− F bond activation is
reported. Treatment of gem‐difluoroalkenes with racemic benzyl electrophiles in the …

Organoboron and organosilane compounds are widely used in organic synthesis and
pharmaceuticals. In addition, the C–F bond functionalization is a useful tool for the …

Comprehensive Summary Monofluoroalkenes are important and versatile privileged
components in pharmacologically relevant molecules. Here, we report a method for the …

The activation and functionalization of C–F bonds for the construction of C–C and C–X
bonds have drawn significant research attention in recent years. However, the chemo-and …

The example of iron-catalyzed cross-electrophile coupling of aryl chlorides with unactivated
alkyl chlorides via an iron/B 2 pin 2 catalytic system has been developed.(Hetero) aryl …

The auxiliary function of a carbonyl group in the tunable defluorophosphination and
defluorophosphorylation of trifluoromethylated enones with P (O)-containing compounds …

Photosensitization of organometallics is a privileged strategy that enables challenging
transformations in transition-metal catalysis. However, the usefulness of such photocatalyst …

This review aims to highlight the role of silicon in drug discovery. Silicon and carbon are
often regarded as being similar with silicon located directly beneath carbon in the same …