Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Raman spectroscopy, an ideal tool for studying the physical properties and applications of metal–organic frameworks (MOFs)

J Sunil, C Narayana, G Kumari… - Chemical Society …, 2023 - pubs.rsc.org
Metal–organic frameworks (MOFs) are a unique family of materials constructed by
coordinating metal ions or clusters to bridging organic ligands. Many of these materials are …

Progress in the development of flexible metal–organic frameworks for hydrogen storage and selective separation of its isotopes

J Park, A Adhikary, HR Moon - Coordination Chemistry Reviews, 2023 - Elsevier
Between 2018 and 2050, global energy usage is expected to increase by approximately
50% because of rapid technological advancements, high population growth rates, and …

Ozone decomposition by a manganese-organic framework over the entire humidity range

ZB Sun, YN Si, SN Zhao, QY Wang… - Journal of the American …, 2021 - ACS Publications
Ground-level ozone (O3) is one of the main airborne pollutants detrimental to human health
and ecosystems. However, the designed synthesis of high-performance O3 elimination …

Metal–organic frameworks in Germany: From synthesis to function

JD Evans, B Garai, H Reinsch, W Li, S Dissegna… - Coordination Chemistry …, 2019 - Elsevier
Metal–organic frameworks (MOFs) are constructed from a combination of inorganic and
organic units to produce materials which display high porosity, among other unique and …

Soft mode metal-linker dynamics in carboxylate MOFs evidenced by variable-temperature infrared spectroscopy

AB Andreeva, KN Le, L Chen, ME Kellman… - Journal of the …, 2020 - ACS Publications
Through comprehensive analysis of carboxylate-based metal–organic frameworks (MOFs),
we present general evidence that challenges the common perception of MOF metal-linker …

The role of phonons in switchable MOFs: a model material perspective

AEJ Hoffman, I Senkovska, L Abylgazina… - Journal of Materials …, 2023 - pubs.rsc.org
The large cell volume changes of switchable metal–organic frameworks (MOFs) render them
as promising functional materials. Low-frequency phonon modes are known to influence the …

Crystal size versus paddle wheel deformability: selective gated adsorption transitions of the switchable metal–organic frameworks DUT-8 (Co) and DUT-8 (Ni)

S Ehrling, I Senkovska, V Bon, JD Evans… - Journal of Materials …, 2019 - pubs.rsc.org
Switchable pillared layer metal–organic frameworks M2 (2, 6-ndc) 2 (dabco)(DUT-8 (M), M=
Ni, Co, 2, 6-ndc= 2, 6-naphthalenedicarboxylate, dabco= 1, 4-diazabicyclo-[2.2. 2] octane …

Structure, Thermal Stability, and Spectroscopic Properties of Triclinic Double Sulfate AgEu(SO4)2 with Isolated SO4 Groups

YG Denisenko, VV Atuchin, MS Molokeev… - Inorganic …, 2018 - ACS Publications
Silver–europium double sulfate AgEu (SO4) 2 was obtained by solid-phase reaction
between Ag2SO4 and Eu2 (SO4) 3. The crystal structure of AgEu (SO4) 2 was determined …

Unfolding the terahertz spectrum of soft porous crystals: rigid unit modes and their impact on phase transitions

AEJ Hoffman, I Senkovska, J Wieme, A Krylov… - Journal of Materials …, 2022 - pubs.rsc.org
Phase transitions in flexible metal–organic frameworks or soft porous crystals are mediated
by low-frequency phonons or rigid-unit modes. The alteration of specific building blocks may …