Phosphorus–nitrogen compounds. Part 54. syntheses of chiral amino-4-fluorobenzyl-spiro (N/O) cyclotriphosphazenes: structural and stereogenic properties

ÖF Mutlu, A Binici, A Okumuş, G Elmas… - New Journal of …, 2021 - pubs.rsc.org
Although tetrahedrally coordinated pendant-armed heterocyclic phosphazenes are
considerably stable, the stereogenic properties of their inorganic ring systems are much less …

The comparative reactions of 2‐cis‐4‐ansa and spiro cyclotetraphosphazenes with difunctional ligands: Structural and stereogenic properties, electrochemical …

A Okumuş, G Elmas, Z Kılıç, A Binici… - Applied …, 2021 - Wiley Online Library
In this study, two kinds of compounds, namely, mono‐ferrocenyl‐2‐cis‐4‐dichloro‐ansa‐(2,
4‐ansa; 3) and mono‐ferrocenyl‐spiro‐(spiro; 4) hexachlorocyclotetraphosphazenes, were …

Phosphorus-nitrogen compounds. Part 62. Preparation of tetraaminobis (4-fluorobenzyl) spiro (N/N) cyclotriphosphazenes: Chemical, structural characterizations …

A Okumuş, G Elmas, A Binici, B Aydın, L Açık… - Inorganica Chimica …, 2022 - Elsevier
Substitution reaction of hexachlorocyclotriphosphazatriene (trimer; N 3 P 3 Cl 6; HCCP) with
N, N'-bis (4-fluorobenzyl) ethane-1, 2-diamine (1) gave the starting compound tetrachlorobis …

Phosphorus–nitrogen compounds. Part 58. Syntheses, structural characterizations and biological activities of 4-fluorobenzyl-spiro (N/O) cyclotriphosphazene …

A Binici, G Elmas, A Okumuş… - Journal of …, 2023 - Taylor & Francis
Abstract The starting compound, tetrachloro-4-fluorobenzyl-spiro (N/O) cyclotriphosphazene
(2), was synthesized from the substitution reaction of hexachlorocyclotriphosphazatriene …

Phosphorus–nitrogen compounds: part 53—synthesis, characterization, cytotoxic and antimicrobial activity, DNA interaction and molecular docking studies of new …

Ö İşcan, R Cemaloğlu, N Asmafiliz, CT Zeyrek, Z Kılıç… - Molecular Diversity, 2022 - Springer
Mono-/dispirocyclotriphosphazenes with pendant arm (s) are robust, but they are less
investigated inorganic ring systems. In this study, a series of mono (3 and 4)-and …

Phosphorus–nitrogen compounds. Part 65. Novel diansa-spiro-cyclotetraphosphazenes: synthesis, characterization, bioactivity and electrochemical properties, and …

G Mutlu, A Okumuş, G Elmas, Z Kılıç, R Güzel… - New Journal of …, 2022 - pubs.rsc.org
In this investigation, the substitution reaction of octachlorocyclotetraphosphazene, N4P4Cl8
(tetramer, OCCP, 1), with sodium 3-(N-ferrocenylmethylamino)-1-propanoxide (L1) was …

Phosphorus–nitrogen compounds. Part 64. Comparative reactions of spiro and ansa (N/O) cyclotetraphosphazenes with bulky (4-fluorobenzyl) N/N and N/O donor …

G Elmas, A Binici, M Yakut, A Okumuş, Z Kılıç… - New Journal of …, 2022 - pubs.rsc.org
The reaction of octachlorocyclotetraphosphazene, N4P4Cl8 (1)(OCCP, tetramer), with an
equimolar amount of sodium 3-(N-ferrocenylmethylamino)-1-propanoxide (L1) resulted in …

Phosphorus-nitrogen compounds. Part 56. Comparative syntheses and spectral properties of multiheterocyclic 2-cis-4-ansa and spiro-ferrocenyl (N/O) …

A Binici, A Okumuş, M Yakut, G Elmas… - … , Sulfur, and Silicon …, 2022 - Taylor & Francis
In the present study, two types of starting compounds; hexachloro (N/O)-
cyclotetraphosphazenes containing mono-ferrocenyl-pendant arm, namely, mono-ferrocenyl …

Coumarin–Phosphazenes: Enhanced Photophysical Properties from Hybrid Materials

ME Şahin, F Biryan, E Çalışkan… - Inorganic Chemistry, 2024 - ACS Publications
Phosphazenes have drawn a great deal of interest over the past 20 years as a potentially
useful building block for the fabrication of fluorescent materials. The main objective of this …

Phosphorus–nitrogen compounds: part 70. Syntheses of tetraaminomono/bis (4-fluorobenzyl) spiro (N/N) cyclotriphosphazenes: structural characterization, Hirshfeld …

A Okumuş, G Elmas, A Binici, E Tunca… - New Journal of …, 2023 - pubs.rsc.org
Both starting phosphazenes, tetrachloromono-and tetrachlorobis-(4-fluorobenzyl) monospiro
(N/N) cyclotriphosphazenes (1 and 2) were synthesized by the substitution reactions of …