Metal–organic framework magnets

AE Thorarinsdottir, TD Harris - Chemical reviews, 2020 - ACS Publications
Metal–organic frameworks represent the ultimate chemical platform on which to develop a
new generation of designer magnets. In contrast to the inorganic solids that have dominated …

Probing magnetic interactions in metal–organic frameworks and coordination polymers microscopically

PJ Saines, NC Bristowe - Dalton Transactions, 2018 - pubs.rsc.org
Materials with magnetic interactions between their metal centres play a tremendous role in
modern technologies and can exhibit unique physical phenomena. In recent years …

A Zn azelate MOF: combining antibacterial effect

C Tamames-Tabar, E Imbuluzqueta, N Guillou… - …, 2015 - pubs.rsc.org
A novel biocompatible and bioactive Metal–Organic Framework (BioMOF), named BioMIL-5
(Bioactive Materials from Institut Lavoisier), was hydrothermally synthesized from a Zn2+ salt …

Ultrathin 2D coordination polymer nanosheets by surfactant-mediated synthesis

SC Junggeburth, L Diehl, S Werner… - Journal of the …, 2013 - ACS Publications
Low-dimensional nanostructures offer a host of intriguing properties which are distinct from
those of the bulk material, owing to size-confinement effects and amplified surface areas …

A series of mixed-ligand 2D and 3D coordination polymers assembled from a novel multifunctional pyridine-tricarboxylate building block: hydrothermal syntheses …

JZ Gu, YH Cui, J Wu, AM Kirillov - RSC advances, 2015 - pubs.rsc.org
A series of novel mixed-ligand coordination polymers, namely,{[Cd2 (μ4-L)(μ3-OH)(phen) 2]·
2H2O} n (1),{[Mn3 (μ5-L) 2 (phen) 2 (H2O)]· H2O} n (2),[Cd2 (μ3-L)(H2biim) 2 (μ2-Hbiim)] n …

Searching beyond Gd for magnetocaloric frameworks: magnetic properties and interactions of the Ln (HCO 2) 3 series

PJ Saines, JAM Paddison, PMM Thygesen… - Materials …, 2015 - pubs.rsc.org
This study probes the magnetic properties and interactions of the Ln (HCO2) 3 (Ln= Tb3+–
Er3+) frameworks. We show that the magnetocaloric effect of Tb (HCO2) 3 is significantly …

Isomer-directed structural diversity and its effect on the nanosheet exfoliation and magnetic properties of 2, 3-dimethylsuccinate hybrid frameworks

PJ Saines, M Steinmann, JC Tan, HHM Yeung… - Inorganic …, 2012 - ACS Publications
The structures of seven new transition metal frameworks featuring Mn, Co, or Zn and either
the meso or chiral d and l isomers of the 2, 3-dimethylsuccinate ligand are reported …

Synthesis, structures and photoluminescence properties of a series of alkaline earth metal-based coordination networks synthesized using thiophene-based linkers

X Chen, AM Plonka, D Banerjee… - Crystal growth & …, 2013 - ACS Publications
Three new 3-D coordination networks were synthesized using alkaline-earth metal centers,
calcium, and strontium, with 2, 5-thiophenedicarboxylate (TDC) as the organic linker.[Ca2 …

Probing ferroic transitions in a multiferroic framework family: a neutron diffraction study of the ammonium transition metal formates

JMM Lawler, P Manuel, AL Thompson… - Dalton Transactions, 2015 - pubs.rsc.org
This study probes the magnetic and ferroelectric ordering of the NH4M (HCO2) 3 (M= Mn2+,
Fe2+, Co2+ and Ni2+) frameworks using neutron diffraction, improving the understanding of …

Cobalt adipate, Co (C 6 H 8 O 4): antiferromagnetic structure, unusual thermal expansion and magnetoelastic coupling

PJ Saines, PT Barton, M Jura, KS Knight… - Materials …, 2014 - pubs.rsc.org
Co adipate, Co (C6H8O4), has been found to order near 10 K into a magnetic structure
featuring sheets of tetrahedral Co cations coupled antiferromagnetically in two dimensions …