Dynamic and reconfigurable materials from reversible network interactions

MJ Webber, MW Tibbitt - Nature Reviews Materials, 2022 - nature.com
Polymer materials provide solutions to some of the most pressing environmental,
manufacturing and health-care challenges. Traditional thermoplastic and thermoset …

Biobased vitrimers: Towards sustainable and adaptable performing polymer materials

MA Lucherelli, A Duval, L Avérous - Progress in Polymer Science, 2022 - Elsevier
In the last decades, Covalent Adaptable Networks (CAN) appeared as an innovative
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …

Self-healing polymers

S Wang, MW Urban - Nature Reviews Materials, 2020 - nature.com
Self-healing is the capability of a material to recover from physical damage. Both physical
and chemical approaches have been used to construct self-healing polymers. These include …

Vitrimers: Current research trends and their emerging applications

J Zheng, ZM Png, SH Ng, GX Tham, E Ye, SS Goh… - Materials Today, 2021 - Elsevier
The development of recyclable plastics is a key research focus in today's world due to their
environmental issues, and non-renewability concerns. Recently, vitrimeric materials have …

Elastic vitrimers: Beyond thermoplastic and thermoset elastomers

J Luo, Z Demchuk, X Zhao, T Saito, M Tian, AP Sokolov… - Matter, 2022 - cell.com
Thermoset elastomers are widely used in industry and frontier research due to their
advantage of mechanical robustness, high thermal/chemical resistance, and good …

Vitrimers: Permanently crosslinked polymers with dynamic network topology

NJ Van Zee, R Nicolaÿ - Progress in Polymer Science, 2020 - Elsevier
The study of synthetic organic polymers rapidly expanded since Staudinger's recognition of
the covalent structure of macromolecules. Today, these materials are far from just an …

Adaptable crosslinks in polymeric materials: resolving the intersection of thermoplastics and thermosets

GM Scheutz, JJ Lessard, MB Sims… - Journal of the American …, 2019 - ACS Publications
The classical division of polymeric materials into thermoplastics and thermosets based on
covalent network structure often implies that these categories are distinct and irreconcilable …

Dynamic covalent chemistry in polymer networks: a mechanistic perspective

JM Winne, L Leibler, FE Du Prez - Polymer Chemistry, 2019 - pubs.rsc.org
The incorporation of dynamic covalent linkages within and between polymer chains brings
new properties to classical thermosetting polymer formulations, in particular in terms of …

Vitrimers: directing chemical reactivity to control material properties

M Guerre, C Taplan, JM Winne, FE Du Prez - Chemical science, 2020 - pubs.rsc.org
The development of more sustainable materials with a prolonged useful lifetime is a key
requirement for a transition towards a more circular economy. However, polymer materials …

Reprocessable cross-linked polymer networks: are associative exchange mechanisms desirable?

BR Elling, WR Dichtel - ACS Central Science, 2020 - ACS Publications
Covalent adaptable networks (CANs) are covalently cross-linked polymers that may be
reshaped via cross-linking and/or strand exchange at elevated temperatures. They …