Four-membered monocyclic aza-heterocycles, 1 despite their indisputable importance as
bioactive compounds and pharmaceutical tools, have received by the chemical community …

The structure of Fischer carbene complexes (FCCs) is electron deficient. If bearing an α, β‐
unsaturated system, it can generate a wide variety of compounds by undergoing many …

The seminal report by Hegedus in 1982, showing that alkoxychromium (0) carbenes reacted
with imines under bright Colorado sunlight to yield β-lactams, marked the beginning of a key …

Non-heteroatom-stabilized group 6 metal carbene complexes are a particular type of Fischer
carbene complex that lacks stabilizing heteroatoms. The aim of this review is to provide a …

The knowledge of the reactivity of Fischer carbene complexes in electron transfer processes
is still in the early stage of development, but interesting advances are foreseeable in this …

Half‐sandwich manganese methylenephosphonium complexes [Cp (CO) 2Mn (η2‐R2P C
(H) Ph)] BF4 were obtained in high yield through a straightforward reaction sequence …

This review article covers the development of Fischer carbene complexes since the year
2000, with specific focus on carbene complexes bearing metal-containing fragments as …

The joint computational (TD-DFT) experimental study of the UV− vis spectroscopy of
alkoxychromium (0) carbene complexes accurately assigns the vertical transitions …

Transmetalation reactions from chromium (0) Fischer carbene complexes to late‐transition‐
metal complexes (palladium (0), copper (I), and rhodium (I)) have been studied …

The mechanism of the thermal formation of ketenimine complexes through the reaction of
group 6 (chromium and tungsten) and 8 (iron) Fischer carbenes and isocyanides has been …