[HTML][HTML] Molecular elucidation of CO2 methanation over a highly active, selective and stable LaNiO3/CeO2-derived catalyst by in situ FTIR and NAP-XPS

JA Onrubia-Calvo, S López-Rodríguez… - Applied Catalysis B …, 2024 - Elsevier
The CO 2 methanation mechanism over the highly active (TOF= 75.1 h− 1), selective (>
92%) and stable 10% LaNiO 3/CeO 2-derived catalyst is still unresolved. The surface of the …

Carbon Encapsulation of Supported Metallic Iridium Nanoparticles: An in Situ Transmission Electron Microscopy Study and Implications for Hydrogen Evolution …

P Liu, A Klyushin, P Chandramathy Surendran… - ACS …, 2023 - ACS Publications
Carbon-supported metal nanoparticles (NPs) comprise an important class of heterogeneous
catalysts. The interaction between the metal and carbon support influences the overall …

Application of Time-Resolved Synchrotron X-ray Absorption Spectroscopy in an Energy Conversion Reaction

X Shen, D Wu, H Zhang, X Liu, L Cao… - The Journal of Physical …, 2023 - ACS Publications
The rational design of high-efficiency catalysts is hindered by the knowledge of active sites,
which always experience dynamic transformations within different time scales. In this regard …

In situ/Operando Synchrotron Radiation Analytical Techniques for CO2/CO Reduction Reaction: From Atomic Scales to Mesoscales

YN Xu, B Mei, Q Xu, HQ Fu, XY Zhang… - Angewandte Chemie …, 2024 - Wiley Online Library
Electrocatalytic carbon dioxide/carbon monoxide reduction reaction (CO (2) RR) has
emerged as a prospective and appealing strategy to realize carbon neutrality for …

Revealing the effect of metal-support interactions at the Ni/In2O3 (111) interface on the selective CO2 hydrogenation

Y Ding, J Chen, X Lian, Z Tian, X Geng, Y Wang… - Applied Catalysis B …, 2024 - Elsevier
In 2 O 3-supported Ni catalysts exhibit remarkable catalytic activity and selectivity in CO 2
hydrogenation to methanol, but the underlying mechanisms and metal-oxide interactions …

Vision 2050: Reaction Engineering Roadmap

P Bollini, M Diwan, P Gautam, RL Hartman… - ACS Engineering …, 2023 - ACS Publications
This perspective provides the collective opinions of a dozen chemical reaction engineers
from academia and industry. In this sequel to the “Vision 2020: Reaction Engineering …

State of the surface during CO hydrogenation over Ni (111) and Ni (211) probed by operando X-ray photoelectron spectroscopy

D Degerman, P Lömker, CM Goodwin… - The Journal of …, 2023 - ACS Publications
The state of the surface near-region during CO hydrogenation of Ni (111) and Ni (211)
single crystal surfaces was investigated using various gas mixtures between 150 and 500 …

Demonstrating Pressure Jumping as a Tool to Address the Pressure Gap in High Pressure Photoelectron Spectroscopy of CO and CO2 Hydrogenation on Rh(211)

D Degerman, CM Goodwin, P Lömker… - …, 2024 - Wiley Online Library
Operando probing by x‐ray photoelectron spectroscopy (XPS) of certain hydrogenation
reactions are often limited by the scattering of photoelectrons in the gas phase. This work …

State-of-the-Art In Situ Technologies for Unravelling the Dynamic Structure Evolution during Acidic Oxygen Evolution Reaction

Q Meng, M Xiao, C Liu, W Xing… - The Journal of Physical …, 2024 - ACS Publications
Oxygen evolution reaction (OER) plays an important role in water electrolysis, which is
considered a promising pathway for hydrogen energy storage. However, the harsh catalytic …

Chemical Doping by Fluorination and Its Impact on All Energy Levels of π-Conjugated Systems

D Bischof, Y Radiev, MW Tripp… - The Journal of …, 2023 - ACS Publications
Halogenation of organic molecules causes chemical shifts of C1s core-level binding
energies that are commonly used as fingerprints to identify chemical species. Here, we use …