Ultrafast Chemistry of Water Radical Cation, H2O•+, in Aqueous Solutions

J Ma, F Wang, M Mostafavi - Molecules, 2018 - mdpi.com
Oxidation reactions by radicals constitute a very important class of chemical reactions in
solution. Radiation Chemistry methods allow producing, in a controlled way, very reactive …

Capture of hydroxyl radicals by hydronium cations in water microdroplets

D Xing, Y Meng, X Yuan, S Jin, X Song… - Angewandte …, 2022 - Wiley Online Library
Despite the high stability of bulk water, water microdroplets possess strikingly different
properties, such as the presence of hydroxyl radicals (OH⋅) at the air–water interface …

Observation of the fastest chemical processes in the radiolysis of water

ZH Loh, G Doumy, C Arnold, L Kjellsson… - Science, 2020 - science.org
Elementary processes associated with ionization of liquid water provide a framework for
understanding radiation-matter interactions in chemistry and biology. Although numerous …

Femtosecond proton transfer in urea solutions probed by X-ray spectroscopy

Z Yin, YP Chang, T Balčiūnas, Y Shakya, A Djorović… - Nature, 2023 - nature.com
Proton transfer is one of the most fundamental events in aqueous-phase chemistry and an
emblematic case of coupled ultrafast electronic and structural dynamics,. Disentangling …

First-principles simulations of biological molecules subjected to ionizing radiation

KA Omar, K Hasnaoui… - Annual Review of Physical …, 2021 - annualreviews.org
Ionizing rays cause damage to genomes, proteins, and signaling pathways that normally
regulate cell activity, with harmful consequences such as accelerated aging, tumors, and …

Imaging the short-lived hydroxyl-hydronium pair in ionized liquid water

MF Lin, N Singh, S Liang, M Mo, JPF Nunes… - Science, 2021 - science.org
The radiolysis of water is ubiquitous in nature and plays a critical role in numerous
biochemical and technological applications. Although the elementary reaction pathways for …

Alignment of electronic energy levels at electrochemical interfaces

J Cheng, M Sprik - Physical Chemistry Chemical Physics, 2012 - pubs.rsc.org
The position of electronic energy levels in a phase depends on the surface potentials at its
boundaries. Bringing two phases in contact at an interface will alter the surface potentials …

Direct tracking of ultrafast proton transfer in water dimers

K Schnorr, M Belina, S Augustin, H Lindenblatt… - Science …, 2023 - science.org
Upon ionization, water forms a highly acidic radical cation H2O+· that undergoes ultrafast
proton transfer (PT)—a pivotal step in water radiation chemistry, initiating the production of …

Attosecond spectroscopy of size-resolved water clusters

X Gong, S Heck, D Jelovina, C Perry, K Zinchenko… - Nature, 2022 - nature.com
Electron dynamics in water are of fundamental importance for a broad range of phenomena,–
, but their real-time study faces numerous conceptual and methodological challenges …

Inner-shell-ionization-induced femtosecond structural dynamics of water molecules imaged at an x-ray free-electron laser

T Jahnke, R Guillemin, L Inhester, SK Son, G Kastirke… - Physical Review X, 2021 - APS
The ultrafast structural dynamics of water following inner-shell ionization is a crucial issue in
high-energy radiation chemistry. We have exposed isolated water molecules to a short x-ray …