Environmental speciation of actinides

K Maher, JR Bargar, GE Brown Jr - Inorganic chemistry, 2013 - ACS Publications
Although minor in abundance in Earth's crust (U, 2–4 ppm; Th, 10–15 ppm) and in seawater
(U, 0.003 ppm; Th, 0.0007 ppm), light actinides (Th, Pa, U, Np, Pu, Am, and Cm) are …

Mineral–water interface reactions of actinides

H Geckeis, J Lützenkirchen, R Polly, T Rabung… - Chemical …, 2013 - ACS Publications
Reactions of the light actinide ions (Th to Cm) at the mineral− aqueous solution interface
have attracted much attention during recent years. Initially research was mainly driven by the …

Iron redox cycling in layered clay minerals and its impact on contaminant dynamics: A review

Q Fan, L Wang, Y Fu, Q Li, Y Liu, Z Wang… - Science of the Total …, 2023 - Elsevier
A majority of clay minerals contain Fe, and the redox cycling of Fe (III)/Fe (II) in clay minerals
has been extensively studied as it may fuel the biogeochemical cycles of nutrients and …

Cesium sorption reversibility and kinetics on illite, montmorillonite, and kaolinite

CB Durrant, JD Begg, AB Kersting, M Zavarin - Science of the Total …, 2018 - Elsevier
Understanding sorption and desorption processes is essential to predicting the mobility of
radionuclides in the environment. We investigate adsorption/desorption of cesium in both …

Characterization of americium and curium complexes with the protein lanmodulin: a potential macromolecular mechanism for actinide mobility in the environment

GJP Deblonde, JA Mattocks, H Wang… - Journal of the …, 2021 - ACS Publications
Anthropogenic radionuclides, including long-lived heavy actinides such as americium and
curium, represent the primary long-term challenge for management of nuclear waste. The …

Experimental and computational study on the inhibitory effect of phytic acid on U (VI) biomineralization by Shewanella putrefaciens

X Lu, Y Zhang, W Cheng, Y Liu, X Wu, X Li… - Chemical Engineering …, 2022 - Elsevier
Abstract Uranyl (UO 2 2+) species with hexavalent U (VI) oxidation state is the most
ubiquitous form of uranium in natural minerals, underground water, contaminated soils, and …

Plutonium mobility and reactivity in a heterogeneous clay rock barrier accented by synchrotron-based microscopic chemical imaging

U Kaplan, S Amayri, J Drebert, D Grolimund… - Scientific Reports, 2024 - nature.com
The long-term safe disposal of radioactive waste corresponds to a challenging responsibility
of present societies. Within deep geological waste disposal concepts, host rocks correspond …

Np (V) Retention at the Illite du Puy Surface

B Schacherl, C Joseph, A Beck, P Lavrova… - Environmental …, 2023 - ACS Publications
In this study, Np (V) retention on Illite du Puy (IdP) was investigated since it is essential for
understanding the migration behavior of Np in argillaceous environments. The presence of …

Colloid-borne forms of tetravalent actinides: a brief review

H Zänker, C Hennig - Journal of contaminant hydrology, 2014 - Elsevier
Abstract Tetravalent actinides, An (IV), are usually assumed to be little mobile in near-neutral
environmental waters because of their low solubility. However, there are certain …

Pu (V) and Pu (IV) sorption to montmorillonite

JD Begg, M Zavarin, P Zhao, SJ Tumey… - … science & technology, 2013 - ACS Publications
Plutonium (Pu) adsorption to and desorption from mineral phases plays a key role in
controlling the environmental mobility of Pu. Here we assess whether the adsorption …