Nickel-rich and cobalt-free layered oxide cathode materials for lithium ion batteries

Y Luo, H Wei, L Tang, Z Wang, Z He, C Yan… - Energy storage …, 2022 - Elsevier
For conventional cathode materials, cobalt plays an important role, but the cobalt content of
lithium battery cathode materials must be reduced because of the scarcity of cobalt …

Ni‐rich/Co‐poor layered cathode for automotive Li‐ion batteries: promises and challenges

X Wang, YL Ding, YP Deng… - Advanced Energy …, 2020 - Wiley Online Library
To pursue a higher energy density (> 300 Wh kg− 1 at the cell level) and a lower cost (<
$125 kWh− 1 expected at 2022) of Li‐ion batteries for making electric vehicles (EVs) long …

Challenges and strategies to advance high‐energy nickel‐rich layered lithium transition metal oxide cathodes for harsh operation

GL Xu, X Liu, A Daali, R Amine… - Advanced functional …, 2020 - Wiley Online Library
Nickel‐rich layered lithium transition metal oxides (LiNi1− x− yCoxMnyO2 and LiNi1− x−
yCoxAlyO2, x+ y≤ 0.2) are the most attractive cathode materials for the next generation …

Chemical, structural, and electronic aspects of formation and degradation behavior on different length scales of Ni‐rich NCM and Li‐rich HE‐NCM cathode materials …

L de Biasi, B Schwarz, T Brezesinski… - Advanced …, 2019 - Wiley Online Library
In order to satisfy the energy demands of the electromobility market, both Ni‐rich and Li‐rich
layered oxides of NCM type are receiving much attention as high‐energy‐density cathode …

Is cobalt needed in Ni-rich positive electrode materials for lithium ion batteries?

H Li, M Cormier, N Zhang, J Inglis, J Li… - Journal of The …, 2019 - iopscience.iop.org
As a derivative of LiNiO 2, NCA (LiNi 1-xy Co x Al y O 2) is widely used in the electric vehicle
industry because of its high energy density. It is thought that Co and Al both play important …

Surface/interface structure degradation of Ni‐rich layered oxide cathodes toward lithium‐ion batteries: fundamental mechanisms and remedying strategies

L Liang, W Zhang, F Zhao, DK Denis… - Advanced Materials …, 2020 - Wiley Online Library
Nickel‐rich layered transition‐metal oxides with high‐capacity and high‐power capabilities
are established as the principal cathode candidates for next‐generation lithium‐ion …

Stress accumulation in Ni-rich layered oxide cathodes: Origin, impact, and resolution

Y Su, Q Zhang, L Chen, L Bao, Y Lu, S Chen… - Journal of Energy …, 2022 - Elsevier
Abstract LiNi x Co y Mn z O 2 (NCM, x+ y+ z= 1) is one of the most promising cathode
candidates for high energy density lithium-ion batteries (LIBs). Due to the potential in …

In-situ formation of hybrid Li3PO4-AlPO4-Al (PO3) 3 coating layer on LiNi0. 8Co0. 1Mn0. 1O2 cathode with enhanced electrochemical properties for lithium-ion battery

Z Feng, R Rajagopalan, D Sun, Y Tang… - Chemical engineering …, 2020 - Elsevier
Irreversible phase transition and surface residual lithium, which cause the fast capacity
fading of LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811), are the main obstacles that hinder their …

Synthesis and mechanism of high structural stability of nickel-rich cathode materials by adjusting Li-excess

Z Yu, X Qu, T Wan, A Dou, Y Zhou, X Peng… - … Applied Materials & …, 2020 - ACS Publications
It has been a long-term challenge to improve the phase stability of Ni-rich LiNi x Mn y Co1–x–
y O2 (x≥ 0.6) transition metal (TM) oxides for large-scale applications. Herein, a new …

Enhanced surface chemical and structural stability of Ni-rich cathode materials by synchronous lithium-ion conductor coating for lithium-ion batteries

R Qian, Y Liu, T Cheng, P Li, R Chen… - ACS applied materials …, 2020 - ACS Publications
Ni-rich cathode materials LiNi x Co y Mn1–x–y O2 (x≥ 0.6) have attracted much attention
due to their high capacity and low cost. However, they usually suffer from rapid capacity …