Semimetal-functionalised polyoxovanadates

KY Monakhov, W Bensch, P Kögerler - Chemical Society Reviews, 2015 - pubs.rsc.org
Polyoxovanadates (POVs), known for their wide applicability and relevance in chemical,
physical and biological sciences, are a subclass of polyoxometalates and usually self …

Metallosupramolecular approach toward multifunctional magnetic devices for molecular spintronics

M Castellano, R Ruiz-Garcia, J Cano… - Coordination Chemistry …, 2015 - Elsevier
The work presented in this review constitutes a successful extension of our group's research
on the chemistry and physics of dinuclear copper (II) metallacyclophanes with aromatic …

Mixed-valence clusters: Prospects for single-molecule magnetoelectrics

A Palii, S Aldoshin, B Tsukerblat - Coordination Chemistry Reviews, 2021 - Elsevier
In this review we summarize the results of recent studies of the mechanisms of
magnetoelectric effect in mixed-valence molecules. Consideration of fairly different systems …

Single ion magnets based on lanthanoid polyoxomolybdate complexes

JJ Baldoví, Y Duan, C Bustos, S Cardona-Serra… - Dalton …, 2016 - pubs.rsc.org
Polyoxometalate (POM) chemistry has recently offered excellent examples of single ion
magnets (SIMs) and molecular spin qubits. Compared with conventional coordination …

Electrically Switchable Magnetic Molecules: Inducing a Magnetic Coupling by Means of an External Electric Field in a Mixed‐Valence Polyoxovanadate Cluster

S Cardona‐Serra, JM Clemente‐Juan… - … A European Journal, 2015 - Wiley Online Library
Herein we evaluate the influence of an electric field on the coupling of two delocalized
electrons in the mixed‐valence polyoxometalate (POM)[GeV14O40] 8−(in short V14) by …

Spin switching in molecular quantum cellular automata based on mixed-valence tetrameric units

A Palii, B Tsukerblat, JM Clemente-Juan… - The Journal of …, 2016 - ACS Publications
In this article we focus on the study of spin effects in a single square-planar mixed-valence
cell comprising two electrons and in coupled molecular cells for quantum cellular automata …

Dipyridyl-anderson-polyoxometalate built-in metal–organic frameworks for aerobic photooxidation

L Yan, AJ Li, JX Du, Y Xiong, SL Huang - Applied Catalysis A: General, 2024 - Elsevier
Abstract Two POM-MOFs Co-1 and Ni-1 were synthesized from pyridyl-Anderson-POM
linker. When combined with [Ru (bpy) 3] 2+, Ru (bpy) 3@ Co-1 showed excellent …

Design of Magnetic Polyoxometalates for Molecular Spintronics and as Spin Qubits

JJ Baldoví, S Cardona-Serra, A Gaita-Ariño… - Advances in Inorganic …, 2017 - Elsevier
In the past decades, POMs have been used as minimal models in Molecular Magnetism,
since they are a convenient playing ground to study fundamental phenomena such as …

Molecules designed to contain two weakly coupled spins with a photoswitchable spacer

JS Uber, M Estrader, J Garcia… - … A European Journal, 2017 - Wiley Online Library
Controlling the charges and spins of molecules lies at the heart of spintronics. A
photoswitchable molecule consisting of two independent spins separated by a …

Electric field control of the optical properties in magnetic mixed-valence molecules

A Palii, JM Clemente-Juan, B Tsukerblat… - Chemical …, 2014 - pubs.rsc.org
We propose the use of an electric field stimulus to strongly affect the optical properties of
ferromagnetic mixed-valence (MV) dimers. This proposal is based on the prediction of an …