A review of the selective catalytic reduction of aromatic nitro compounds into aromatic amines, isocyanates, carbamates, and ureas using CO
AM Tafesh, J Weiguny - Chemical reviews, 1996 - ACS Publications
Carbon monoxide is an important reagent for the functionalization of organic compounds
and is used in a wide variety of industrial processes such as carbonylation of alkenes to …
and is used in a wide variety of industrial processes such as carbonylation of alkenes to …
Progress in hydroformylation and carbonylation
M Beller, B Cornils, CD Frohning… - Journal of Molecular …, 1995 - Elsevier
The last 15 years of hydroformylation and carbonylation chemistry are reviewed, including
technical and commercial aspects.
technical and commercial aspects.
Catalytic synthesis of isocyanates or carbamates from nitroaromatics using Group VIII transition metal catalysts
F Paul - Coordination Chemistry Reviews, 2000 - Elsevier
In order to produce various isocyanates, catalyzed carbonylations of nitroaromatic
compounds constitute a set of very appealing reactions for industry. These environmentally …
compounds constitute a set of very appealing reactions for industry. These environmentally …
Transition Metal Catalyzed Reductive Cyclization Reactions of Nitroarenes and Nitroalkenes
F Ferretti, DR Ramadan, F Ragaini - ChemCatChem, 2019 - Wiley Online Library
Nitroarenes are the entry point for the production of most nitrogen‐containing aromatic
compounds. Thus, any transformation that leads directly from them to the final product allows …
compounds. Thus, any transformation that leads directly from them to the final product allows …
Promoting Reductive Tandem Reactions of Nitrostyrenes with Mo(CO)6 and a Palladium Catalyst To Produce 3H-Indoles
The combination of Mo (CO) 6 and 10 mol% of palladium acetate catalyzes the
transformation of 2-nitroarenes to 3 H-indoles through a tandem cyclization-[1, 2] shift …
transformation of 2-nitroarenes to 3 H-indoles through a tandem cyclization-[1, 2] shift …
Palladium‐Catalyzed Formation of N‐Heteroarenes from Nitroarenes using Molybdenum Hexacarbonyl as the Source of Carbon Monoxide
The development of a method that employs a two‐chamber reaction vessel and uses
molybdenum hexacarbonyl [Mo (CO) 6] as the carbon monoxide (CO) source for the …
molybdenum hexacarbonyl [Mo (CO) 6] as the carbon monoxide (CO) source for the …
Allylic Amination of Cyclohexene Catalyzed by Ruthenium Complexes. A New Reaction Involving an Intermolecular C−H Functionalization
S Cenini, F Ragaini, S Tollari… - Journal of the American …, 1996 - ACS Publications
Transition-metal-mediated intermolecular activation and functionalization of CH bonds is a
topic of high current interest. From another perspective, the functionalization of a simple …
topic of high current interest. From another perspective, the functionalization of a simple …
Reductive coupling of nitroarenes with carboxylic acids–a direct route to amide synthesis
MA Losev, AS Kozlov, VB Kharitonov… - Organic & …, 2023 - pubs.rsc.org
A straightforward and selective way for the preparation of amides from nitroarenes and
carboxylic acids using carbon monoxide as a reductant was developed. This protocol does …
carboxylic acids using carbon monoxide as a reductant was developed. This protocol does …
Subtle balance between various phenanthroline ligands and anions in the palladium-catalyzed reductive carbonylation of nitrobenzene
P Wehman, VE Kaasjager, F Hartl, PCJ Kamer… - …, 1995 - ACS Publications
Aromatic isocyanates and carbamates have become increasingly important ever since the
work of O. Bayer in 1937 led to the formation of polyurethanes from diisocyanates and diols …
work of O. Bayer in 1937 led to the formation of polyurethanes from diisocyanates and diols …
Carbon monoxide as a selective reducing agent in organic chemistry
AA Tsygankov, M Makarova, D Chusov - Mendeleev Communications, 2018 - Elsevier
Carbon monoxide as an example of reducing agent, in contrast to classical reducing agents
(hydrogen and metal hydrides), can provide very high atom precision for reductive addition …
(hydrogen and metal hydrides), can provide very high atom precision for reductive addition …