Carbenes have evolved from transient laboratory curiosities to a robust, diverse, and
surprisingly impactful ligand class. A variety of different carbenes have significantly …

Isolation of cyclic (alkyl) amino carbenes (cAACs) in 2005 has been a major achievement in
the field of stable carbenes due to their better electronic properties. cAACs and bicyclic …

This perspective describes the development of zero-valent species E n (0) of group 13–15
elements. Computational studies providing reinterpretation of bonding involved in well …

Homometallic copper complexes with alkenylidene ligands are discussed as intermediates
in catalysis but the isolation of such complexes has remained elusive. Herein, we report the …

Recently, stable diazoalkenes have received significant attention as a new substance class
in organic chemistry. While their previous synthetic access was exclusively limited to the …

C2 has attracted considerable attention from the scientific community for its debatable
bonding situation. Herein, we show that the global minima of M2B2 and M3B2+ (M= Li, Na) …

Quantum chemical studies using density functional theory were carried out for the (L) 4C4
complexes with L= cAAC, DAC, NHC, SNHC, MIC1, and MIC2. The results show that the title …

Metal ions‐based inorganic‐organic hybrid composites are often reported acting as good to
excellent catalysts with various substrate scopes under milder reaction conditions. The …

The donor ligand bonded singlet (L) 2Si2C containing a bent Si2C unit in the middle has
been studied by theoretical quantum mechanical calculations (NBO, QTAIM, EDA-NOCV …

Kürzlich haben stabile Diazoalkene als neue Substanzklasse in der organischen Chemie
große Aufmerksamkeit erhalten. Während ihr bisheriger synthetischer Zugang …