Spectroelectrochemical sensing: current trends and challenges

J Garoz‐Ruiz, JV Perales‐Rondon, A Heras… - …, 2019 - Wiley Online Library
Spectroelectrochemistry (SEC) has been used for more than 50 years, but this set of
techniques has not been widely used for quantitative analysis. For many years, no …

Photo-dynamics in 2D materials: Processes, tunability and device applications

F Zhang, J Pei, A Baev, M Samoc, Y Ge, PN Prasad… - Physics Reports, 2022 - Elsevier
The past decade has witnessed the rise of low-dimensional materials, such as graphene,
transition metal dichalcogenides, black phosphorus, organic–inorganic hybrid perovskites …

Light Emission Mechanisms in CuInS2 Quantum Dots Evaluated by Spectral Electrochemistry

AS Fuhr, HJ Yun, NS Makarov, H Li, H McDaniel… - ACS …, 2017 - ACS Publications
Luminescent CuInS2 (CIS) quantum dots (QDs) exhibit highly efficient intragap emission
and long, hundreds-of-nanoseconds radiative lifetimes. These spectral properties, distinct …

Reversible electrochemistry of mercury chalcogenide colloidal quantum dot films

M Chen, P Guyot-Sionnest - ACS nano, 2017 - ACS Publications
The absolute positions of the energy levels of colloidal quantum dots of Hg (S, Se, Te),
which are of interest as mid-infrared materials, are determined by electrochemistry. The bulk …

Switching between plasmonic and fluorescent copper sulfide nanocrystals

W Van Der Stam, S Gudjonsdottir… - Journal of the …, 2017 - ACS Publications
Control over the doping density in copper sulfide nanocrystals is of great importance and
determines its use in optoelectronic applications such as NIR optical switches and …

Tuning and Probing the Distribution of Cu+ and Cu2+ Trap States Responsible for Broad-Band Photoluminescence in CuInS2 Nanocrystals

W Van Der Stam, M De Graaf, S Gudjonsdottir… - Acs Nano, 2018 - ACS Publications
The processes that govern radiative recombination in ternary CuInS2 (CIS) nanocrystals
(NCs) have been heavily debated, but recently, several research groups have come to the …

Spectroelectrochemical signatures of surface trap passivation on CdTe nanocrystals

W Van Der Stam, I Du Fossé, G Grimaldi… - Chemistry of …, 2018 - ACS Publications
The photoluminescence (PL) quantum yield of semiconductor nanocrystals (NCs) is
hampered by in-gap trap states due to dangling orbitals on the surface of the nanocrystals …

Electrical control of single-photon emission in highly charged individual colloidal quantum dots

S Morozov, EL Pensa, AH Khan, A Polovitsyn… - Science …, 2020 - science.org
Electron transfer to an individual quantum dot promotes the formation of charged excitons
with enhanced recombination pathways and reduced lifetimes. Excitons with only one or two …

Hot-electron transfer in quantum-dot heterojunction films

G Grimaldi, RW Crisp, S Ten Brinck, F Zapata… - Nature …, 2018 - nature.com
Thermalization losses limit the photon-to-power conversion of solar cells at the high-energy
side of the solar spectrum, as electrons quickly lose their energy relaxing to the band edge …

Spectroelectrochemistry of Colloidal CdSe Quantum Dots

A Ashokan, P Mulvaney - Chemistry of Materials, 2021 - ACS Publications
Solution-phase spectroelectrochemistry was used to study electron injection into colloidal
CdSe quantum dots (QDs) with sizes ranging from 3.4 to 11.1 nm in tetrahydrofuran (THF) …