The crystal chemistry of uranium carboxylates

T Loiseau, I Mihalcea, N Henry, C Volkringer - Coordination Chemistry …, 2014 - Elsevier
The field of uranium carboxylates has been studied for several decades and an important
library of coordination complexes and network solids is now well defined. It mainly concerns …

The size of actinoid (III) ions–structural analysis vs. common misinterpretations

D Lundberg, I Persson - Coordination Chemistry Reviews, 2016 - Elsevier
A fundamental property of ions is their size, a known fact since before the acceptance of the
modern atom model. The common way to describe the size of an ion is to determine its …

Polyoxometalates as ligands to synthesize, isolate and characterize compounds of rare isotopes on the microgram scale

I Colliard, JRI Lee, CA Colla, HE Mason, AM Sawvel… - Nature Chemistry, 2022 - nature.com
The synthesis and study of radioactive compounds are both inherently limited by their
toxicity, cost and isotope scarcity. Traditional methods using small inorganic or organic …

Ligand structure optimization leads to efficient acid-resist Am (III)/Eu (III) separation in n-octanol

Y Liu, M Bao, L Wang, Y Kang, Y Dou, J Qin… - Chemical Engineering …, 2024 - Elsevier
Liquid-liquid extraction is the most wildly adopted industrial Lns/Ans separation approach
which takes advantages of the subtle atomic size differences for Lns and Ans. Preorganized …

[HTML][HTML] Uncovering f-element bonding differences and electronic structure in a series of 1: 3 and 1: 4 complexes with a diselenophosphinate ligand

MB Jones, AJ Gaunt, JC Gordon, N Kaltsoyannis… - Chemical …, 2013 - pubs.rsc.org
Understanding the bonding trends within, and the differences between, the 4f and 5f
element series with soft donor atom ligands will aid elucidation of the fundamental origins of …

Unraveling the complexation mechanism of actinide (III) and lanthanide (III) with a new tetradentate phenanthroline-derived phosphonate ligand

L Xu, N Pu, G Ye, C Xu, J Chen, X Zhang… - Inorganic Chemistry …, 2020 - pubs.rsc.org
The extraction and complexation of trivalent Am (III) and lanthanide (III) with a new
phenanthroline-derived phosphonate ligand, tetrabutyl-(1, 10-phenanthrolin-2, 9-diyl) …

[HTML][HTML] Spectroscopic and computational investigation of actinium coordination chemistry

MG Ferrier, ER Batista, JM Berg, ER Birnbaum… - Nature …, 2016 - nature.com
Actinium-225 is a promising isotope for targeted-α therapy. Unfortunately, progress in
developing chelators for medicinal applications has been hindered by a limited …

Unfolding the extraction and complexation behaviors of trivalent f-block elements by a tetradentate N, O-Hybrid phenanthroline derived phosphine oxide ligand

L Xu, X Yang, Z Wang, S Wang, M Sun, C Xu… - Inorganic …, 2021 - ACS Publications
In this work, a tetradentate N, O-hybrid 2, 9-bis (diphenylphosphine oxide)-1, 10-
phenanthroline (Ph2-BPPhen) ligand was studied for the coextraction of trivalent f-block …

A series of dithiocarbamates for americium, curium, and californium

SK Cary, J Su, SS Galley, TE Albrecht-Schmitt… - Dalton …, 2018 - pubs.rsc.org
Characterizing how actinide properties change across the f-element series is critical for
improving predictive capabilities and solving many nuclear problems facing our society …

Separation of americium from lanthanide by a Task-Specific ionic liquid decorated with 2, 6-Bis-Triazolyl-Pyridine moiety

Q Yan, Y Cai, Z Wang, X Dong, L Yuan, W Feng… - Separation and …, 2022 - Elsevier
A novel task-specific ionic liquid (PyTri-TSIL) decorated with 2, 6-bis-triazolyl-pyridine moiety
was synthesized via the click chemistry route. The performance of PyTri-TSIL in an ionic …