Recently the fruitful merger of organoboron chemistry and photocatalysis has come to the
forefront of organic synthesis, resulting in the development of new technologies to access …

Radical transformations are powerful in organic synthesis for the construction of molecular
scaffolds and introduction of functional groups. In radical difunctionalization reactions, the …

Operationally simple strategies to assemble boron containing organic frameworks are highly
enabling in organic synthesis. While conventional retrosynthetic logic has engendered many …

Although highly appealing for rapid access of molecular complexity, multi‐functionalization
of alkenes that allows incorporation of more than two functional groups remains a prominent …

Described here is a simple and efficient method to prepare organoboron compounds
through α-deprotonation and functionalization of benzylboronates. In addition to alkyl …

In recent years, remarkable advances in the functionalization of remote alkyl C (sp3)–H
bonds or aldehydic C (sp2)–H bonds enabled by intermolecular radical addition to CC …

Three-component 1, 2-carboamination of vinyl boronic esters with alkyl/aryl lithium reagents
and N-chloro-carbamates/carboxamides is presented. Vinylboron ate complexes generated …

A photocatalyzed 1, 3-boron shift of allylboronic esters is reported. The boron atom migration
through the allylic carbon skeleton proceeds via consecutive 1, 2-boron migrations and …

Herein, we report a photoinduced 1, 7-hydrosulfonylation of allylic ethers and amides via a
sequential Pd-mediated 1, 5-HAT process and Pd-catalyzed allylic nucleophilic attack of …

A novel and efficient radical-modulated difunctionalization of vinyl enynes has been
disclosed using TEMPO as a radical regulator. Facile access to structurally diverse 3-bromo …