The enhancement of the reactivity of peroxides, particularly hydrogen peroxide and
alkylhydroperoxides, in the presence of vanadium catalysis is a very well known process …

Organohalide is one of the most important and useful compounds in organic chemistry,
broadly embodied in diverse bioactive molecules, organic materials and agrochemicals …

Chemical halogenation is an important transformation in organic synthesis. Halogenations
involve the use of reactive and toxic halogens (X 2) or hydrogen halides (HX). Chemical …

Catalysis by transition metal ions in oxidation reactions with hydrogen peroxide and alkyl
hydroperoxides is a leading topic in the pursuit of more sustainable and selective processes …

Coordination complexes of vanadium (5+) played a key role in understanding the structure
and mechanism of vanadium-dependent haloperoxidases, particularly the effects of …

Vanadium-dependent haloperoxidases are a class of enzymes that catalyze oxidation
reactions with halides to form halogenated organic products and water. These enzymes …

Density functional theory has been used to investigate structural, electronic and reactivity
properties of complexes related to the peroxo forms of vanadium haloperoxidases (VHPO) …

The quadrupolar nucleus 51 V is particularly well suited for NMR due to its rather small
nuclear quadrupole moment and high sensitivity. The use of vanadium compounds in …

Vanadium haloperoxidases are one of the few enzymes in nature that utilize a vanadium
center and catalyze the halogenation of substrates through the biosynthesis of hypohalite …

The geometry of 32 VIVO2+ complexes with different donor set, electric charge, geometry,
arrangement of the ligands with respect to the V O bond and type of ligand was calculated …