Enantioselective C(sp2)–C(sp3) Bond Construction by Ni Catalysis

LM Chen, SE Reisman - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus After decades of palladium dominating the realm of transition-metal-catalyzed
cross-coupling, recent years have witnessed exciting advances in the development of new …

Low-energy photoredox catalysis

DC Cabanero, T Rovis - Nature Reviews Chemistry, 2024 - nature.com
With the advent of photoredox catalysis, new synthetic paradigms have been established
with many novel transformations being achieved. Nevertheless, modern photoredox …

Synthesis of Unnatural Amino Acids via Ni/Ag Electrocatalytic Cross-Coupling

G Laudadio, P Neigenfind, R Chebolu… - Organic …, 2024 - ACS Publications
A simple protocol is outlined herein for rapid access to enantiopure unnatural amino acids
(UAAs) from trivial glutamate and aspartate precursors. The method relies on Ag/Ni …

Stereoselective amino alcohol synthesis via chemoselective electrocatalytic radical cross-couplings

J Sun, S Wang, KC Harper, Y Kawamata, PS Baran - Nature Chemistry, 2025 - nature.com
Amino alcohols are vital in natural products, pharmaceuticals and agrochemicals, and as
key building blocks for various applications. Traditional synthesis methods often rely on …

Cross‐Coupling of Gaseous Alkanes with (Hetero) Aryl Bromides via Dual Nickel/Photoredox Catalysis

AM Nair, P Martínez‐Balart… - Angewandte …, 2024 - Wiley Online Library
Gaseous alkanes represent the most abundant carbon‐based chemical feedstocks in our
planet. However, the intrinsic inertness of their C− H bonds has rendered the use of these …

Interfacial Science for Electrosynthesis

T Kim, YJ Kim, A Wuttig - Current Opinion in Electrochemistry, 2024 - Elsevier
Interfacial science and electroorganic syntheses are inextricably linked because all
electrochemical reactions occur at the interface between the electrode and the solution …

Constructing N‐Containing Poly(p‐Phenylene) (PPP) Films Through A Cathodic‐Dehalogenation Polymerization Method

X Wang, L Zhang, J Wu, M Xue, Q Gu, J Qi… - Small …, 2024 - Wiley Online Library
Developing the films of N‐containing unsubstituted poly (p‐phenylene)(PPP) films for
diverse applications is significant and highly desirable because the replacement of sp2 C …

Simple Synthesis of Unnatural Amino Acids via Ni/Ag-Electrocatalytic Cross-Coupling

G Laudadio, P Neigenfind, R Chebolu, VD Blasczak… - 2024 - chemrxiv.org
A simple protocol is outlined herein for rapid access to enantiopure unnatural amino acids
from trivial glutamate and aspartate precursors. The method relies on Ag/Ni-electrocatalytic …

Heterocoupling Two Similar Benzyl Radicals by Dual Photoredox/Cobalt Catalysis

W Yang, Z Zhao, Y Lan, Z Dong, R Chang… - Angewandte Chemie … - Wiley Online Library
Transition‐metal‐regulated radical cross coupling enables the selective bonding of two
distinct transient radicals, whereas the catalytic method for sorting two almost identical …

Reimagining Enantioselective Aminoalcohol Synthesis via Chemoselective Electrocatalytic Radical Cross Couplings

J Sun, S Wang, K Harper, Y Kawamata, P Baran - 2024 - chemrxiv.org
Aminoalcohols are expressed in natural products, blockbuster pharmaceuticals,
agrochemicals, and key building blocks for innumerable society-benefitting applications …