Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Symmetry strategies for high performance lanthanide-based single-molecule magnets

JL Liu, YC Chen, ML Tong - Chemical Society Reviews, 2018 - pubs.rsc.org
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

FS Guo, BM Day, YC Chen, ML Tong, A Mansikkamäki… - Science, 2018 - science.org
Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Molecular magnetism

NF Chilton - Annual Review of Materials Research, 2022 - annualreviews.org
Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …

Emerging trends on designing high-performance dysprosium (III) single-molecule magnets

TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks

J Zhang, L Liu, C Zheng, W Li, C Wang… - nature …, 2023 - nature.com
Spin-based sensors have attracted considerable attention owing to their high sensitivities.
Herein, we developed a metallofullerene-based nano spin sensor to probe gas adsorption …

Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets

AB Canaj, S Dey, ER Martí, C Wilson… - Angewandte Chemie …, 2019 - Wiley Online Library
Following a novel synthetic strategy where the strong uniaxial ligand field generated by the
Ph3SiO−(Ph3SiO−= anion of triphenylsilanol) and the 2, 4‐di‐tBu‐PhO−(2, 4‐di‐tBu‐PhO …

Computational design of magnetic molecules and their environment using quantum chemistry, machine learning and multiscale simulations

A Lunghi, S Sanvito - Nature Reviews Chemistry, 2022 - nature.com
Having served as a playground for fundamental studies on the physics of d and f electrons
for almost a century, magnetic molecules are now becoming increasingly important for …

Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond

F Liu, G Velkos, DS Krylov, L Spree, M Zalibera… - Nature …, 2019 - nature.com
Engineering intramolecular exchange interactions between magnetic metal atoms is a
ubiquitous strategy for designing molecular magnets. For lanthanides, the localized nature …