While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …

Over the last 15 years, a plethora of research has provided major insights into the structure
and function of hydrogenase enzymes. This has led to the important development of …

This perspective article reviews the recent important progress in electrocatalytic hydrogen
production catalyzed by earth-abundant metal complexes. The catalysts are divided into two …

This tutorial review is aimed at chemical scientists interested in understanding and
exploiting the remarkable catalytic behavior of the hydrogenases. The key structural features …

Generation of hydrogen by reduction of two protons by two electrons can be catalysed by
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …

This article reviews published literature on the electrochemical reduction and oxidation of
complexes containing the Fe2S2 core characteristic of the active site of [FeFe] …

Extended investigation of electrocatalytic generation of dihydrogen using [(μ-1, 2-
benzenedithiolato)][Fe (CO) 3] 2 has revealed that weak acids, such as acetic acid, can be …

This review focuses on electron and proton transfers involving hexacarbonyl and substituted
{2Fe2S} complexes inspired from the active site of the [FeFe]-hydrogenases ([FeFe] …

Complexes [{(μ-SCH2) 2NCH2C6H5}{Fe (CO) 2L1}{Fe (CO) 2L2}](L1= CO, L2= P (Pyr) 3, 2;
L1= L2= P (Pyr) 3, 3) were prepared, which have the lowest reduction potentials for the …