Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Since its advent two decades ago, asymmetric organo/transition-metal combined catalysis
(AOMC), including cooperative catalysis and relay catalysis, has leveraged redistribution of …

Metal-hydride-catalyzed hydroalkylation of 1, 3-dienes with enolizable carbonyl compounds
is an atom-and step-economical method for preparing chiral molecules with allylic …

The cooperation and interplay between organic and metal catalyst systems is of utmost
importance in nature and chemical synthesis. Here innovative and selective cooperative …

Synergistic catalysis is a synthetic strategy wherein both the nucleophile and the
electrophile are simultaneously activated by two separate and distinct catalysts to afford a …

The combination of transition metal catalysis and organocatalysis as a new and exciting
research area has attracted increasing attention as it can enable the development of …

The catalysis by primary and secondary amines of electrophilic substitution reactions in the
R-position of carbonyl compounds and related reactions via enamine intermediates is called …

Multicomponent reactions that involve interception of onium ylides through Aldol, Mannich,
and Michael addition with corresponding bench-stable acceptors have demonstrated broad …

In general, DA reactions can be classified into two types of suprafacial [π4s+ π2s]
cycloadditions:(i) the normal and (ii) inverse-electron-demand DA reactions (Scheme 1) …