Fluids and electrolytes under confinement in single-digit nanopores

NR Aluru, F Aydin, MZ Bazant, D Blankschtein… - Chemical …, 2023 - ACS Publications
Confined fluids and electrolyte solutions in nanopores exhibit rich and surprising physics
and chemistry that impact the mass transport and energy efficiency in many important …

Microscopic simulations of electrochemical double-layer capacitors

G Jeanmairet, B Rotenberg, M Salanne - Chemical reviews, 2022 - ACS Publications
Electrochemical double-layer capacitors (EDLCs) are devices allowing the storage or
production of electricity. They function through the adsorption of ions from an electrolyte on …

Theory and simulations of ionic liquids in nanoconfinement

S Kondrat, G Feng, F Bresme, M Urbakh… - Chemical …, 2023 - ACS Publications
Room-temperature ionic liquids (RTILs) have exciting properties such as nonvolatility, large
electrochemical windows, and remarkable variety, drawing much interest in energy storage …

Fluids at the nanoscale: from continuum to subcontinuum transport

N Kavokine, RR Netz, L Bocquet - Annual Review of Fluid …, 2021 - annualreviews.org
Nanofluidics has firmly established itself as a new field in fluid mechanics, as novel
properties have been shown to emerge in fluids at the nanometric scale. Thanks to recent …

Anomalously low dielectric constant of confined water

L Fumagalli, A Esfandiar, R Fabregas, S Hu, P Ares… - Science, 2018 - science.org
The dielectric constant ε of interfacial water has been predicted to be smaller than that of
bulk water (ε≈ 80) because the rotational freedom of water dipoles is expected to decrease …

Modeling of emergent memory and voltage spiking in ionic transport through angstrom-scale slits

P Robin, N Kavokine, L Bocquet - Science, 2021 - science.org
Recent advances in nanofluidics have enabled the confinement of water down to a single
molecular layer. Such monolayer electrolytes show promise in achieving bioinspired …

Nanoconfinement-mediated water treatment: from fundamental to application

J Qian, X Gao, B Pan - Environmental Science & Technology, 2020 - ACS Publications
Safe and clean water is of pivotal importance to all living species and the ecosystem on
earth. However, the accelerating economy and industrialization of mankind generate water …

Confinement-controlled aqueous chemistry within nanometric slit pores: Focus review

D Munoz-Santiburcio, D Marx - Chemical Reviews, 2021 - ACS Publications
In this Focus Review, we put the spotlight on very recent insights into the fascinating world of
wet chemistry in the realm offered by nanoconfinement of water in mechanically rather rigid …

Advances in atomistic modeling and understanding of drying shrinkage in cementitious materials

MJA Qomi, L Brochard, T Honorio, I Maruyama… - Cement and Concrete …, 2021 - Elsevier
Despite more than a century of research, drying shrinkage still causes unwanted stresses
and cracks in our concrete infrastructures. This is partly due to the lack of understanding of …

Molecular streaming and its voltage control in ångström-scale channels

T Mouterde, A Keerthi, AR Poggioli, SA Dar, A Siria… - Nature, 2019 - nature.com
Over the past decade, the ability to reduce the dimensions of fluidic devices to the
nanometre scale (by using nanotubes,,,–or nanopores,,,,–, for example) has led to the …