Despite the long and extensive research, the mechanism of action of zinc-dependent
alcohol dehydrogenase on the molecular level is still uncertain. The present state of …

In this work, we describe the results obtained by our group on the synthesis of metallic
thiolato complexes by the electrochemical oxidation of a sacrificial anode in a non-aqueous …

X-ray absorption fine structure (XAFS) spectra have been measured for a series of
structurally characterized zinc model complexes that mimic the zinc sites found in …

X-ray absorption spectroscopy, using the analytical methodology described in the previous
paper, has been used to determine the ligation of the essential zinc ions in cobalamin …

Zinc (II) and copper (II) complexes of two new potentially pentadentate ligands based on
methyl 2-aminocyclopent-1-ene-1-dithiocarboxylate with pendent pyrazolyl groups …

Publisher Summary This chapter discusses the chemistry of sterically hindered thiolate
complexes. The chapter presents a survey that covers the chemistry of transition metal and …

Studies of the transcriptional repression of the Ni-specific permease encoded by the P nik
operon by Escherichia coli NikR using a LacZ reporter assay establish that the NikR …

Nine new pseudotetrahedral Zn (II) complexes of the heteroscorpionate ligands (3-tert-butyl-
2-hydroxy (or thio)-5-methylphenyl) bis (3, 5-dimethylpyrazolyl) methane, L1OH or L2SH …

Materials and Methods Materials. Water was bidistilled over quartz. All salts were of
analytical grade (pa). 2-Mercaptoethanol and Fractogel TSK-DEAE-F were obtained …

The mechanism of oxidation of benzaldehyde to benzoic acid catalyzed by horse liver
alcohol dehydrogenase (HLADH) has been investigated using the HLADH structure at 2.1 Å …