Pnictogen‐Bonding Enzymes
The objective of this study was to create artificial enzymes that capitalize on pnictogen
bonding, a σ‐hole interaction that is essentially absent in biocatalysis. For this purpose …
bonding, a σ‐hole interaction that is essentially absent in biocatalysis. For this purpose …
Core‐Alkynylated Fluorescent Flippers: Altered Ultrafast Photophysics to Track Thick Membranes
KKP Pamungkas, I Fureraj, L Assies… - Angewandte Chemie …, 2024 - Wiley Online Library
Fluorescent flippers have been introduced as small‐molecule probes to image membrane
tension in living systems. This study describes the design, synthesis, spectroscopic and …
tension in living systems. This study describes the design, synthesis, spectroscopic and …
Asparagusic Golgi Trackers
S Saidjalolov, XX Chen, J Moreno, M Cognet… - JACS Au, 2024 - ACS Publications
Thiol-mediated uptake (TMU) is thought to occur through dynamic covalent cascade
exchange networks. Here we show that the cascade accounting for TMU of asparagusic acid …
exchange networks. Here we show that the cascade accounting for TMU of asparagusic acid …
Hydrophobic Interfacing of Fluorescent Membrane Probes
Fluorescent flippers have been introduced as small‐molecule probes to image membrane
tension in living systems. While the hydrophilic headgroup region has been modified …
tension in living systems. While the hydrophilic headgroup region has been modified …
A Fluorogenic Substrate for Quinoline Reduction: Pnictogen‐Bonding Catalysis in Aqueous Systems
It is often said that pnictogen‐bonding catalysis, and σ‐hole catalysis in general, would not
work in aqueous systems because the solvent would interfere as an overcompetitive …
work in aqueous systems because the solvent would interfere as an overcompetitive …
Fluorescent Membrane Probes Obey the Israelachvili Rules
F Bayard, S Matile - Helvetica Chimica Acta, 2024 - Wiley Online Library
When developing fluorescent membrane probes, we naturally tend to focus on the
fluorophore itself. In this study, we show that sometimes it can be beneficial to shift attention …
fluorophore itself. In this study, we show that sometimes it can be beneficial to shift attention …
[PDF][PDF] HELVETICA
G Renno, QX Zhang, A Frontera, N Sakai, S Matile - researchgate.net
It is often said that pnictogen-bonding catalysis, and σ-hole catalysis in general, would not
work in aqueous systems because the solvent would interfere as an overcompetitive …
work in aqueous systems because the solvent would interfere as an overcompetitive …