Aqueous iron (IV)–oxo complex: an emerging powerful reactive oxidant formed by iron (II)-based advanced oxidation processes for oxidative water treatment

Z Wang, W Qiu, S Pang, Q Guo, C Guan… - … Science & Technology, 2022 - ACS Publications
High-valent iron (IV)–oxo complexes are of great significance as reactive intermediates
implicated in diverse chemical and biological systems. The aqueous iron (IV)–oxo complex …

Removal of organic compounds by nanoscale zero-valent iron and its composites

Q Li, Z Chen, H Wang, H Yang, T Wen, S Wang… - Science of the Total …, 2021 - Elsevier
During the latest several decades, the continuous development of the economy and industry
has brought more and more serious organic pollutants to the natural environment, which …

Fenton/Fenton-like processes with in-situ production of hydrogen peroxide/hydroxyl radical for degradation of emerging contaminants: Advances and prospects

Y Liu, Y Zhao, J Wang - Journal of Hazardous Materials, 2021 - Elsevier
Fenton processes based on the reaction between Fe 2+ and H 2 O 2 to produce hydroxyl
radicals, have been widely studied and applied for the degradation of toxic organic …

Is sulfate radical really generated from peroxydisulfate activated by iron (II) for environmental decontamination?

Z Wang, J Jiang, S Pang, Y Zhou, C Guan… - Environmental …, 2018 - ACS Publications
It is well documented that the traditional Fenton reagent (ie, the combination of Fe (II) and
H2O2) produces hydroxyl radical (• OH) under acidic conditions, while at near-neutral pH …

Both Fe (IV) and radicals are active oxidants in the Fe (II)/peroxydisulfate process

H Dong, Y Li, S Wang, W Liu, G Zhou… - … Science & Technology …, 2020 - ACS Publications
The question of whether Fe (IV) or SO4•–is the dominant intermediate in the Fe (II)-activated
peroxydisulfate process [Fe (II)/PDS process] remains unanswered. In this study, besides Fe …

A critical review of the application of chelating agents to enable Fenton and Fenton-like reactions at high pH values

Y Zhang, M Zhou - Journal of hazardous materials, 2019 - Elsevier
To overcome the drawback of low pH requirement of the classical Fenton reaction,
researchers have applied chelating agents to form complexes with Fe and enable Fenton …

Oxalated zero valent iron enables highly efficient heterogeneous Fenton reaction by self-adapting pH and accelerating proton cycle

X Zhang, H Sun, Y Shi, C Ling, M Li, C Liang, F Jia… - Water research, 2023 - Elsevier
Heterogeneous Fenton reactions of zero-valent iron (ZVI) requires the sufficient release of
Fe (II) to catalyze the H 2 O 2 decomposition. However, the rate-limiting step of proton …

Simultaneous reduction of carbon dioxide and energy harvesting using RGO-based SiO2-TiO2 nanocomposite for supercapacitor and microbial electrosynthesis

AH Anwer, M Shoeb, F Mashkoor, A Ali… - Applied Catalysis B …, 2023 - Elsevier
Nowadays, developing a simple, economical, and scalable approach for producing energy
storage and harvesting devices remains challenging. Herein, we developed a mesoporous …

Arsenic contamination, consequences and remediation techniques: a review

R Singh, S Singh, P Parihar, VP Singh… - … and environmental safety, 2015 - Elsevier
The exposure to low or high concentrations of arsenic (As), either due to the direct
consumption of As contaminated drinking water, or indirectly through daily intake of As …

Treatment of organic pollutants by homogeneous and heterogeneous Fenton reaction processes

B Jain, AK Singh, H Kim, E Lichtfouse… - Environmental Chemistry …, 2018 - Springer
Nowadays, the water ecosystem is being polluted due to the rapid industrialization and
massive use of antibiotics, fertilizers, cosmetics, paints, and other chemicals. Chemical …