This review is the counterpart of a 2018 Chemical Reviews article (Adero, PO; Amarasekara,
H.; Wen, P.; Bohé, L.; Crich, D. Chem. Rev. 2018, 118, 8242–8284) that examined the …

Advances in carbohydrate chemistry have certainly made common oligosaccharides much
more accessible. However, many current methods still rely heavily upon specialized …

Recent developments in stereoselective 1, 2-cis glycosylation that have emerged during the
past decade are surveyed herein. For detailed coverage of the previous achievements in the …

The nature of the first genetic polymer is the subject of major debate. Although the 'RNA
world'theory suggests that RNA was the first replicable information carrier of the prebiotic era …

Synthesis of oligosaccharides has, for the past couple of decades, been greatly improved by
new methods and the ongoing development of new technologies, such as automation in …

The efficient synthesis of long, branched, and complex carbohydrates containing multiple 1,
2‐cis glycosidic linkages is a long‐standing challenge. Here, we report a merging reagent …

Conspectus Glycans are complex compounds consisting of sugars linked glycosidically,
existing either as pure polysaccharides or as part of glycoconjugates. They are prevalent in …

Regio-and 1, 2-cis-stereoselective chemical glycosylation of unprotected glycosyl acceptors
has been in great demand for the efficient synthesis of natural glycosides. However …

O-Picoloyl groups at remote positions can mediate the course of glycosylation reactions by
providing high facial selectivity for the H-bond-mediated attack of the glycosyl acceptor. A …

Carbohydrates involving glycoconjugates play a pivotal role in many life processes. Better
understanding toward glycobiological events including the structure–function relationship of …