The transition metal-catalysed hydroboration reaction

SJ Geier, CM Vogels, JA Melanson… - Chemical Society …, 2022 - pubs.rsc.org
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Recent strategies in the nucleophilic dearomatization of pyridines, quinolines, and isoquinolines

M Escolano, D Gaviña, G Alzuet-Piña… - Chemical …, 2024 - ACS Publications
Dearomatization reactions have become fundamental chemical transformations in organic
synthesis since they allow for the generation of three-dimensional complexity from two …

An unprecedented 2-fold interpenetrated lvt open framework built from Zn6 ring seamed trivacant polyoxotungstates used for photocatalytic synthesis of pyridine …

X Huang, S Liu, G Liu, Y Tao, C Wang, Y Zhang… - Applied Catalysis B …, 2023 - Elsevier
Solar-driven straightforward one-step synthesis of pyridine derivatives in the absence of
photosensitizer is of considerable interest but greatly challenging in synthetic and medicinal …

Small molecule activation with bimetallic systems: a landscape of cooperative reactivity

M Navarro, JJ Moreno, M Pérez-Jiménez… - Chemical …, 2022 - pubs.rsc.org
There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …

Implementation of cooperative designs in polarized transition metal systems—significance for bond activation and catalysis

B Chatterjee, WC Chang, S Jena, C Werle - ACS Catalysis, 2020 - ACS Publications
Bond activation and catalysis are central to the development of a sustainable energy system.
Frustrated Lewis Pairs have conceptually revolutionized the activation of inert chemical …

Gold–manganese bimetallic redox coupling with light

S Xia, W Li, H Chen, C Zhu, J Han… - Journal of the American …, 2023 - ACS Publications
The classical Au (I)/Au (III) redox couple chemistry has been limited to constructing C–C and
C–X bonds, and thus, the exploration of the elementary reaction of gold redox coupling is …

Manganese‐Catalyzed Hydroborations with Broad Scope

P Ghosh, A Jacobi von Wangelin - Angewandte Chemie, 2021 - Wiley Online Library
Reductive transformations of easily available oxidized matter are at the heart of synthetic
manipulation and chemical valorization. The applications of catalytic hydrofunctionalization …

Copper‐Catalyzed Oxidative [1+2+1+2] Cascade Cyclization of N,N‐Dimethyl Enaminones with Benzylamines: A Facile Access to Functionalized 1,4 …

Y Sun, Z Chai, D Liu, M Zhang, L Chen… - … A European Journal, 2023 - Wiley Online Library
Using benzylamines as the C4 source of 1, 4‐dihydropyridines (1, 4‐DHPs), a Cu‐catalyzed
oxidative [1+ 2+ 1+ 2] cascade cyclization for the synthesis of 1, 4‐DHPs was firstly …

Intermediates, isolation and mechanistic insights into zinc hydride-catalyzed 1, 2-regioselective hydrofunctionalization of N-heteroarenes

RK Sahoo, N Sarkar, S Nembenna - Inorganic Chemistry, 2022 - ACS Publications
The conjugated bis-guanidinate-supported zinc hydride [{LZnH} 2; L={(ArHN)(ArN)–C═ N–
C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](I)-catalyzed highly demanding exclusive 1, 2 …