The chemistry of diiron complexes has seen a recent renaissance, due to the prominent role
played by the element iron in the development of sustainable synthetic processes and the …

Vinylalkylidene transition metal complexes have been extensively used as 'multitalent tools'
in organic synthesis, covering a broad field of applications. The vinylalkylidene ligands can …

Diiron µ‐aminocarbyne compounds, 1a–e, are prepared in two steps from Fe2Cp2 (CO) 4,
negating the need for difficult purification procedures of intermediate species; they are …

Diiron complexes with bridging hydrocarbyl ligands and containing CO and Cp ligands (Cp=
η5-C5H5) have been investigated as possible electrocatalysts for H2 production. In …

Insertion of propyne or 2-butyne into the Fe–carbyne bond belonging to the fragment
[Fe2Cp2 (CO)(μ-CO){μ-CNMe (R)}]+(R= Me or Xyl= 2, 6-C6H3Me2) was investigated via …

The reactivity of diiron bis-cyclopentadienyl cationic complexes containing a vinyliminium
ligand coordinated to a diiron scaffold and decorated with a ferrocenyl group,[1a–g] …

Regio-and stereoselective nucleophilic attack of cyanide (from NBu4CN) to cationic diiron
vinyliminium compounds [Fe2Cp2 (CO)(μ-CO){μ-η1: η3-C (R′) C (R ″) CNMe2}] CF3SO3 …

The one-electron reduction of a diiron cationic complex revealed unique features: cleavage
of the diiron structure occurred despite a multidentate bridging C3 ligand and was …

This is a review of papers published in the year 2004 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon–transition metal double or triple bond.

The diiron vinyliminium complexes [Fe2 {μ-η1: η3-C (R′) C (H) CN (Me)(R)}(μ-
CO)(CO)(Cp) 2][SO3CF3](R= Me, R′= SiMe3 (1a); R= Me, R′= CH2OH (1b); R= CH2Ph …