Metal sites in zeolites: synthesis, characterization, and catalysis

Q Zhang, S Gao, J Yu - Chemical reviews, 2022 - ACS Publications
Zeolites with ordered microporous systems, distinct framework topologies, good spatial
nanoconfinement effects, and superior (hydro) thermal stability are an ideal scaffold for …

The Oxygenate-Mediated Conversion of COx to Hydrocarbons─On the Role of Zeolites in Tandem Catalysis

J Xie, U Olsbye - Chemical reviews, 2023 - ACS Publications
Decentralized chemical plants close to circular carbon sources will play an important role in
shaping the postfossil society. This scenario calls for carbon technologies which valorize …

Molecular understanding of the catalytic consequence of ketene intermediates under confinement

W Chen, G Li, X Yi, SJ Day, KA Tarach… - Journal of the …, 2021 - ACS Publications
Neutral ketene is a crucial intermediate during zeolite carbonylation reactions. In this work,
the roles of ketene and its derivates (viz., acylium ion and surface acetyl) associated with …

Synthetic routes of clean hydrocarbons fuels and oxygenates by catalytic conversions of carbon oxides

HS Jung, BG Kim, JW Bae - Applied Catalysis B: Environmental, 2023 - Elsevier
The emission controls of carbon oxides (CO x) are crucial to fulfill carbon neutrality, where
CO x is a useful building block for chemical synthesis. Therefore, CO x conversions have …

A carbonylation zeolite with specific nanosheet structure for efficient catalysis

J Yao, Q Wu, J Fan, S Komiyama, X Yong, W Zhang… - ACS …, 2021 - ACS Publications
Up to now, the member of zeolite family has expanded to more than 230. However, only little
part of them have been reported as catalysts used in reactions. Discovering potential …

Ferrierite nanosheets with preferential Al locations as catalysts for carbonylation of dimethyl ether

J Tuo, J Wang, X Gong, C Zhai, H Xu, T Xue, J Jiang… - Fuel, 2024 - Elsevier
Enriching Al atoms in T2 and T4 sites of FER zeolite is decisive for achieving high catalytic
activity in the carbonylation reaction of dimethyl ether (DME). Regulating the spatial position …

Morphology Effects of Ferrierite on Bifunctional Cu–ZnO–Al2O3/Ferrierite for Direct Syngas Conversion to Dimethyl Ether

HS Jung, F Zafar, X Wang, TX Nguyen, CH Hong… - ACS …, 2021 - ACS Publications
Different roles of the solid-acid ferrierite zeolite (FER) morphology on the bifunctional Cu–
ZnO–Al2O3 (CZA)-incorporated FER were investigated for the one-step conversion of …

Effects of metal oxide promoters on Cu-ZnO-Al2O3 for one step DME conversion to ethanol by carbonylation and successive hydrogenation

HS Jung, JW Bae - Catalysis Today, 2023 - Elsevier
An indirect ethanol synthesis in terms of carbon neutral strategy by consuming synthesis gas
consists of three separate steps such as syngas to dimethyl ether (DME), DME carbonylation …

[HTML][HTML] Enhancement of the dimethyl ether carbonylation activation via regulating acid sites distribution in FER zeolite framework

Y Guo, S Wang, R Geng, P Wang, S Li, M Dong, Z Qin… - Iscience, 2023 - cell.com
The carbonylation of dimethyl ether (DME) with CO is a key step for ethanol synthesis from
syngas, but traditional mordenite (MOR) zeolite shows low catalytic stability. Herein, various …

Synthesis and catalytic application of nanorod-like FER-type zeolites

W Dai, V Ruaux, X Deng, W Tai, G Wu… - Journal of Materials …, 2021 - pubs.rsc.org
Nanosize dimensions have an important impact on zeolite properties and catalytic
performance in particular. Herein, we develop a direct synthesis route to obtain a nanosized …