New trends in oxidative functionalization of carbon–hydrogen bonds: A review

GB Shul'pin - Catalysts, 2016 - mdpi.com
This review describes new reactions catalyzed by recently discovered types of metal
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …

Tris (pyrazol-1-yl) methane metal complexes for catalytic mild oxidative functionalizations of alkanes, alkenes and ketones

LM Martins, AJL Pombeiro - Coordination Chemistry Reviews, 2014 - Elsevier
This work concerns recent advances (since 2005) in the oxidative functionalization of
alkanes, alkenes and ketones, under mild conditions, catalyzed by homoscorpionate tris …

Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron (II) catalyst

APC Ribeiro, LMDRS Martins, AJL Pombeiro - Green Chemistry, 2017 - pubs.rsc.org
Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron( ii ) catalyst -
Green Chemistry (RSC Publishing) DOI:10.1039/C7GC01993A Royal Society of Chemistry View …

C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

GB Shul'pin - Dalton Transactions, 2013 - pubs.rsc.org
This brief essay consists of a few “exciting stories” devoted to relations within a metal-
complex catalyst between a metal ion and a coordinated ligand. When, as in the case of a …

Zeolites and related materials as catalyst supports for hydrocarbon oxidation reactions

A Martins, N Nunes, AP Carvalho, LM Martins - Catalysts, 2022 - mdpi.com
Catalytic oxidation is a key technology for the conversion of petroleum-based feedstocks into
useful chemicals (eg, adipic acid, caprolactam, glycols, acrylates, and vinyl acetate) since …

C-scorpionate complexes: Ever young catalytic tools

LM Martins - Coordination Chemistry Reviews, 2019 - Elsevier
This work concerns recent advances (since 2014) in the chemistry of C-homoscorpionate tris
(pyrazol-1yl) methanes and in the use of their transition metal complexes as versatile …

Water‐Soluble C‐Scorpionate Complexes–Catalytic and Biological Applications

LM Martins, AJL Pombeiro - European Journal of Inorganic …, 2016 - Wiley Online Library
Recent advances in the synthesis of water‐soluble homoscorpionates of the tris (pyrazol‐1‐
yl) methane type as well as of their water‐soluble metal complexes are reviewed. Moreover …

A hydroperoxo-rebound mechanism of alkane oxidation with hydrogen peroxide catalyzed by binuclear manganese (IV) complex in the presence of an acid with …

GB Shul'pin, DS Nesterov, LS Shul'pina… - Inorganica Chimica …, 2017 - Elsevier
The binuclear manganese (IV) complex [Mn 2 L 2 O 3][PF 6] 2 (L= 1, 4, 7-trimethyl-1, 4, 7-
triazacyclononane)(compound 1) catalyzes very efficiently the oxygenation of alkanes with H …

[HTML][HTML] Catalytic oxidation of cyclohexane with hydrogen peroxide and a tetracopper (II) complex in an ionic liquid

APC Ribeiro, LM Martins, S Hazra… - Comptes Rendus …, 2015 - Elsevier
The catalytic peroxidative oxidation (with H 2 O 2) of cyclohexane in an ionic liquid (IL) using
the tetracopper (II) complex [(CuL) 2 (μ 4-O, O′, O′′, O′′′-CDC)] 2· 2H 2 O [HL= 2-(2 …

Highly dispersed Cu (II), Co (II) and Ni (II) catalysts covalently immobilized on imine-modified silica for cyclohexane oxidation with hydrogen peroxide

R Antony, STD Manickam, P Kollu, PV Chandrasekar… - RSC …, 2014 - pubs.rsc.org
This paper describes the synthesis of Cu (II), Co (II) and Ni (II) catalysts immobilized on
imine-functionalized silica gel through a 3-aminopropyltriethoxysilane linker. The …