Static quenching upon adduct formation: a treatment without shortcuts and approximations
D Genovese, M Cingolani, E Rampazzo… - Chemical Society …, 2021 - pubs.rsc.org
Luminescence quenching is a process exploited in transversal applications in science and
technology and it has been studied for a long time. The luminescence quenching …
technology and it has been studied for a long time. The luminescence quenching …
Polyrotaxanes and the pump paradigm
The year 2022 marks the 30th anniversary of the first reports of polyrotaxanes in the
scientific literature. During the past three decades, many combinations of molecular rings …
scientific literature. During the past three decades, many combinations of molecular rings …
Active mechanisorption driven by pumping cassettes
Over the past century, adsorption has been investigated extensively in equilibrium systems,
with a focus on the van der Waals interactions associated with physisorption and electronic …
with a focus on the van der Waals interactions associated with physisorption and electronic …
Molecular pumps and motors
Pumps and motors are essential components of the world as we know it. From the complex
proteins that sustain our cells, to the mechanical marvels that power industries, much we …
proteins that sustain our cells, to the mechanical marvels that power industries, much we …
Photooxidase mimicking with adaptive coordination molecular capsules
DN Yan, LX Cai, PM Cheng, SJ Hu… - Journal of the …, 2021 - ACS Publications
One important feature of enzyme catalysis is the induced-fit conformational change after
binding substrates. Herein, we report a biomimetic water-soluble molecular capsule …
binding substrates. Herein, we report a biomimetic water-soluble molecular capsule …
The story of the little blue box: a tribute to Siegfried Hünig
The tetracationic cyclophane, cyclobis (paraquat‐p‐phenylene), also known as the little blue
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …
Transamidation-driven molecular pumps
L Binks, C Tian, SDP Fielden… - Journal of the …, 2022 - ACS Publications
We report a new class of synthetic molecular pumps that use a stepwise information ratchet
mechanism to achieve the kinetic gating required to sequester their macrocyclic substrates …
mechanism to achieve the kinetic gating required to sequester their macrocyclic substrates …
Overtemperature-protection intelligent molecular chiroptical photoswitches
Stimuli-responsive intelligent molecular machines/devices are of current research interest
due to their potential application in minimized devices. Constructing molecular …
due to their potential application in minimized devices. Constructing molecular …
Controlling dynamics in extended molecular frameworks
L Feng, RD Astumian, JF Stoddart - Nature Reviews Chemistry, 2022 - nature.com
Molecular machines are essential dynamic components for fuel production, cargo delivery,
information storage and processing in living systems. Scientists have demonstrated that they …
information storage and processing in living systems. Scientists have demonstrated that they …
Radical-pairing-induced molecular assembly and motion
Radical-pairing interactions between conjugated organic π-radicals are relative newcomers
to the inventory of molecular recognition motifs explored in supramolecular chemistry. The …
to the inventory of molecular recognition motifs explored in supramolecular chemistry. The …