A band-gap-graded CZTSSe solar cell with 12.3% efficiency

KJ Yang, DH Son, SJ Sung, JH Sim, YI Kim… - Journal of Materials …, 2016 - pubs.rsc.org
Although Cu2ZnSn (S, Se) 4 (CZTSSe) has attracted attention as an alternative to
CuInGaSe2 (CIGS) as an absorber material in solar cells, its low efficiency is a serious …

Point defects, compositional fluctuations, and secondary phases in non-stoichiometric kesterites

S Schorr, G Gurieva, M Guc… - Journal of Physics …, 2019 - iopscience.iop.org
The efficiency of kesterite-based solar cells is limited by various non-ideal recombination
paths, amongst others by a high density of defect states and by the presence of binary or …

Suppressing element inhomogeneity enables 14.9% efficiency CZTSSe solar cells

Y Li, C Cui, H Wei, Z Shao, Z Wu, S Zhang… - Advanced …, 2024 - Wiley Online Library
Abstract Kesterites, Cu2ZnSn (SxSe1− x) 4 (CZTSSe), solar cells suffer from severe open‐
circuit voltage (VOC) loss due to the numerous secondary phases and defects. The …

Phonon Raman spectroscopy of nanocrystalline multinary chalcogenides as a probe of complex lattice structures

V Dzhagan, AP Litvinchuk, MY Valakh… - Journal of Physics …, 2022 - iopscience.iop.org
Abstract Ternary (I–III–VI) and quaternary (I–II–IV–VI) metal-chalcogenides like CuInS 2 or
Cu 2 ZnSn (S, Se) 4 are among the materials currently most intensively investigated for …

Multiwavelength excitation Raman scattering study of Sb2Se3 compound: fundamental vibrational properties and secondary phases detection

P Vidal-Fuentes, M Guc, X Alcobe, T Jawhari… - 2D …, 2019 - iopscience.iop.org
This work presents a complete analysis of Raman active modes of Sb 2 Se 3 measured by
six different excitation wavelengths from NIR to UV, under different polarization …

On the identification of Sb2Se3 using Raman scattering

A Shongalova, MR Correia, B Vermang… - MRS …, 2018 - cambridge.org
Robust evidences are presented showing that the Raman mode around 250 cm− 1 in the
Sb2Se3 thin films does not belong to this binary compound. The laser power density …

Cu–Zn Cation Disorder in Kesterite Cu2ZnSn(SxSe1–x)4 Solar Cells

AY Zhu, RX Ding, HT Xu, CJ Tong… - ACS Energy …, 2024 - ACS Publications
Cu–Zn cation disorder plays a vital and controversial role in kesterite CuZnSn (S1–x Se x) 4
solar cells. We demonstrate using density functional theory and nonadiabatic molecular …

Is it possible to develop complex S–Se graded band gap profiles in kesterite-based solar cells?

J Andrade-Arvizu, V Izquierdo-Roca… - … applied materials & …, 2019 - ACS Publications
This work presents the development of a novel chalcogenization process for the fabrication
of Cu2ZnSn (S, Se) 4 (CZTSSe or kesterite)-based solar cells that enable the generation of …

Controlling the anionic ratio and gradient in kesterite technology

J Andrade-Arvizu, RF Rubio… - … Applied Materials & …, 2022 - ACS Publications
Accurate anionic control during the formation of chalcogenide solid solutions is fundamental
for tuning the physicochemical properties of this class of materials. Compositional grading is …

Transition-metal oxides for kesterite solar cells developed on transparent substrates

I Becerril-Romero, D Sylla, M Placidi… - … applied materials & …, 2020 - ACS Publications
Fabrication on transparent soda-lime glass/fluorine-doped tin oxide (FTO) substrates opens
the way to advanced applications for kesterite solar cells such as semitransparent, bifacial …