Computational modeling of heterogeneous Ziegler-Natta catalysts for olefins polymerization
Abstract Since 1963, when Karl Ziegler and Giulio Natta were jointly awarded the Nobel
Prize for their discoveries of the catalytic polymerization of olefins with Ti-chlorides and Al …
Prize for their discoveries of the catalytic polymerization of olefins with Ti-chlorides and Al …
Orthogonal synthesis and modification of polymer materials
A Shahrokhinia, P Biswas… - Journal of Polymer …, 2021 - Wiley Online Library
In this review, we detail the progress throughout the years toward developing truly
orthogonal polymerization mechanisms and modification procedures en route to complex …
orthogonal polymerization mechanisms and modification procedures en route to complex …
Light as a catalytic switch for block copolymer architectures: metal–organic insertion/light initiated radical (MILRad) polymerization
We detail a polymer synthetic methodology that merges the techniques of insertion and
radical polymerization methods into a single organometallic catalyst. This metal–organic …
radical polymerization methods into a single organometallic catalyst. This metal–organic …
Mechanistic Study on Effect of Electron Donors in Propylene Polymerization Using the Ziegler–Natta Catalyst
X Guo, L Cui, Y Wang, J Yi, J Sun, Z Liu… - The Journal of Physical …, 2021 - ACS Publications
TiCl4/MgCl2 catalysts are still the main industrial catalyst for isotactic polypropylene at
present. However, the mechanism of isotactic polymerization of propylene has not been fully …
present. However, the mechanism of isotactic polymerization of propylene has not been fully …
Coping with endogeneity and unobserved heterogeneity in real-time clustering critical crash occurrences nested within weather and road surface conditions
A Khoda Bakhshi, MM Ahmed - … journal of injury control and safety …, 2021 - Taylor & Francis
The knot of endogeneity and unobserved heterogeneity are causes of rendering parameter
estimates inconsistent in real-time crash prediction. This study intends to alleviate the …
estimates inconsistent in real-time crash prediction. This study intends to alleviate the …
The Potential Role of Lewis Acid–Base Adducts in Enhancing Stereoselectivity in Ziegler–Natta Catalysts: A DFT Study
Ziegler–Natta (Z–N) systems have been well established as heterogeneous catalysts that
produce isotactic polypropylene and polyethylene with great efficiency. Such systems …
produce isotactic polypropylene and polyethylene with great efficiency. Such systems …
Polyolefin microstructural deconvolution methods: The good, the bad, and the ugly
JBP Soares - The Canadian Journal of Chemical Engineering, 2023 - Wiley Online Library
The deconvolution of the molecular weight distribution (MWD) of polyolefins into Schultz–
Flory most probable distributions has become the standard method to identify the number of …
Flory most probable distributions has become the standard method to identify the number of …
Effects of FeCl3 doping on the performance of MgCl2/TiCl4/DNPB catalyst in 1-hexene polymerization
F Nouri-Ahangarani, M Nekoomanesh… - Polyolefins …, 2017 - poj.ippi.ac.ir
The aim of this study was to examine the effect of catalyst doping on the performance of
MgCl2. EtOH/TiCl4 catalyst system. In this regard, a series of undoped as well as FeCl3 …
MgCl2. EtOH/TiCl4 catalyst system. In this regard, a series of undoped as well as FeCl3 …
Ethylene polymerization using N-Heterocyclic carbene complexes of silver and aluminum
N Kimura, D Takeuchi, S Ogura… - Designed Monomers …, 2023 - Taylor & Francis
Various transition metal catalysts have been utilized for ethylene polymerization. Silver
catalysts have attracted less attention as the catalysts, but are potential for production of high …
catalysts have attracted less attention as the catalysts, but are potential for production of high …
Two new Cd (II)/Zn (II) coordination polymers: Luminescence properties and synergistic treatment activity with ultrasound therapy on uterine fibroids
HM Liu, XN Shang - Designed Monomers and Polymers, 2022 - Taylor & Francis
Through the self-assembly reaction of 5-substituted isophthalic acid and bis (imidazolyl)
ligands with Cd (II) ion or Zn (II) ion, two new coordination polymers with the chemical …
ligands with Cd (II) ion or Zn (II) ion, two new coordination polymers with the chemical …