Promising Catalytic Application by Pincer Metal Complexes: Recent Advances in Hydrogenation of Carbon‐Based Molecules
KK Manar, J Cheng, Y Yang, X Yang, P Ren - ChemCatChem, 2023 - Wiley Online Library
In the last two decades, pincer metal complexes have been highly utilized as catalysts for a
variety of organic transformations in both industrial and social applications. Owing to the …
variety of organic transformations in both industrial and social applications. Owing to the …
(PSiP)Ni-Catalyzed (E)-Selective Semihydrogenation of Alkynes with Molecular Hydrogen
The selective semihydrogenation of alkynes to (E)-alkenes is a challenging transformation
that is of significant synthetic interest. The development of direct hydrogenation catalysts for …
that is of significant synthetic interest. The development of direct hydrogenation catalysts for …
The effect of substituents on the formation of silyl [PSiP] pincer cobalt (I) complexes and catalytic application in both nitrogen silylation and alkene hydrosilylation
Y Dong, P Zhang, Q Fan, X Du, S Xie, H Sun… - Inorganic …, 2020 - ACS Publications
Four different [PSiP]-pincer ligands L1–L4 ((2-Ph2PC6H4) 2SiHR (R= H (L1) and Ph (L2))
and (2-i Pr2PC6H4) 2SiHR′(R′= Ph (L3) and H (L4)) were used to investigate the effect of …
and (2-i Pr2PC6H4) 2SiHR′(R′= Ph (L3) and H (L4)) were used to investigate the effect of …
Metal complexes containing silicon‐based pincer ligands: Reactivity and application in small molecule activation
J Kim - Bulletin of the Korean Chemical Society, 2022 - Wiley Online Library
This review highlights the chemical properties of metal complexes supported by silicon‐
based tridentate ligands. Silicon donors coordinated to a metal exhibit unique characteristics …
based tridentate ligands. Silicon donors coordinated to a metal exhibit unique characteristics …
Square planar cobalt (II) hydride versus T-shaped cobalt (I): structural characterization and dihydrogen activation with PNP–cobalt pincer complexes
LS Merz, CK Blasius, H Wadepohl… - Inorganic Chemistry, 2019 - ACS Publications
The carbazole-based pincer ligand R (CbzPNP) H (R= i Pr, t Bu) has been used for the
synthesis and characterization of various low-and high-spin cobalt complexes. Upon …
synthesis and characterization of various low-and high-spin cobalt complexes. Upon …
Synthesis of Bis (phosphino) silyl Pincer-Supported Iron Hydrides for the Catalytic Hydrogenation of Alkenes
LJ Murphy, MJ Ferguson, R McDonald… - …, 2018 - ACS Publications
The synthesis and characterization of Fe pincer complexes supported by a bis (phosphino)
silyl (PSiP) ligand are described. While four-coordinate species of the type (PSiP) FeX (X …
silyl (PSiP) ligand are described. While four-coordinate species of the type (PSiP) FeX (X …
Highly Selective Nickel‐Catalyzed Isomerization‐Hydroboration of Alkenes Affords Terminal Functionalization at Remote C− H Position
TM Saunders, SB Shepard, DJ Hale… - … A European Journal, 2023 - Wiley Online Library
We report herein the synthesis and characterization of nickel complexes supported by
tridentate and bidentate phosphino (silyl) ancillary ligands, along with the successful …
tridentate and bidentate phosphino (silyl) ancillary ligands, along with the successful …
An air-stable N-heterocyclic [PSiP] pincer iron hydride and an analogous nitrogen iron hydride: synthesis and catalytic dehydration of primary amides to nitriles
Y Wang, H Zhang, S Xie, H Sun, X Li, O Fuhr… - …, 2020 - ACS Publications
An air-stable N-heterocyclic PSiP pincer iron hydride FeH (PMe3) 2 (SiPh (NCH2PPh2)
2C6H4)(4) was synthesized by Si–H activation of a Ph-substituted [PSiP] pincer ligand. The …
2C6H4)(4) was synthesized by Si–H activation of a Ph-substituted [PSiP] pincer ligand. The …
Direct Hydrogenation of Sterically Hindered, Unactivated Alkenes Catalyzed by Phosphino (silyl)‐Nickel Complexes
TM Saunders, KN Roberston, L Turculet - ChemCatChem, 2024 - Wiley Online Library
Abstract Readily accessible (PSi) Ni (II)‐benzyl complexes supported by bidentate
phosphino (silyl) ligation were found to be effective pre‐catalysts for the direct …
phosphino (silyl) ligation were found to be effective pre‐catalysts for the direct …
Formation of N, N, N′, N′-tetramethylethylenediamine via coupling of the two charge reversed C–N bonds of Me 3 NO in the presence of an Eu (ii) bis (trimethylsilyl) …
Y Li, Y Gong - Dalton Transactions, 2024 - pubs.rsc.org
An N, N, N′, N′-tetramethylethylenediamine (TMEDA) complex of Eu (II) was synthesized
via an unprecedented self-aminomethylation of Me3NO in the presence of Eu [N (SiMe3) 2] …
via an unprecedented self-aminomethylation of Me3NO in the presence of Eu [N (SiMe3) 2] …