Kumada Catalyst‐Transfer Polycondensation: Mechanism, Opportunities, and Challenges

A Kiriy, V Senkovskyy, M Sommer - Macromolecular rapid …, 2011 - Wiley Online Library
Kumada catalyst‐transfer polycondensation (KCTP) is a new but rapidly developing method
with great potential for the preparation of well‐defined conjugated polymers (CPs). The …

Diversifying Cross‐Coupling Strategies, Catalysts and Monomers for the Controlled Synthesis of Conjugated Polymers

MA Baker, CH Tsai, KJT Noonan - Chemistry–A European …, 2018 - Wiley Online Library
Chain‐growth polymerization of aromatic building blocks (termed catalyst‐transfer
polycondensation or CTP) has emerged as a powerful method for the controlled synthesis of …

Single‐ended transition state finding with the growing string method

PM Zimmerman - Journal of computational chemistry, 2015 - Wiley Online Library
Reaction path finding and transition state (TS) searching are important tasks in
computational chemistry. Methods that seek to optimize an evenly distributed set of …

Conjugated polymer synthesis via catalyst-transfer polycondensation (CTP): mechanism, scope, and applications

ZJ Bryan, AJ McNeil - Macromolecules, 2013 - ACS Publications
The recent discovery of a living, controlled chain-growth method for synthesizing π-
conjugated polymers has ignited the field and led to the development of many new …

Semiconducting polymers containing tellurium: perspectives toward obtaining high-performance materials

EI Carrera, DS Seferos - Macromolecules, 2015 - ACS Publications
The development of high-carbon-content polymers for optoelectronics is an area of intense
research; however, carbon-rich materials have certain limitations that arise from their …

Impact of copolymer sequence on solid-state properties for random, gradient and block copolymers containing thiophene and selenophene

EF Palermo, AJ McNeil - Macromolecules, 2012 - ACS Publications
Nickel-catalyzed chain-growth copolymerizations of thiophene and selenophene derivatives
afforded well-defined π-conjugated copolymers with narrow molecular weight distributions …

Poly (3-alkyltellurophene) s are solution-processable polyheterocycles

AA Jahnke, B Djukic, TM McCormick… - Journal of the …, 2013 - ACS Publications
The synthesis and characterization of a series of poly (3-alkyltellurophene) s are described.
Polymers are prepared by both electrochemical and Kumada catalyst transfer …

Advances in the controlled polymerization of conjugated polymers

L Verheyen, P Leysen, MP Van Den Eede, W Ceunen… - Polymer, 2017 - Elsevier
This article features recent advances in the synthesis of conjugated polymers via a
controlled polymerization. These polymerizations typically rely on transition metal catalyzed …

Conjugated polymers with repeated sequences of group 16 heterocycles synthesized through catalyst-transfer polycondensation

CH Tsai, A Fortney, Y Qiu, RR Gil, D Yaron… - Journal of the …, 2016 - ACS Publications
Periodic π-conjugated polymers of the group 16 heterocycles (furan, thiophene, and
selenophene) were synthesized with controlled chain lengths and relatively low dispersities …

Ligand-based steric effects in Ni-catalyzed chain-growth polymerizations using bis (dialkylphosphino) ethanes

EL Lanni, JR Locke, CM Gleave, AJ McNeil - Macromolecules, 2011 - ACS Publications
The role of ligand-based steric effects was investigated in the polymerization of 4-bromo-2, 5-
bis (hexyloxy) phenylmagnesium chloride. Three different Ni (LL) Cl2 catalysts were …