Many metal–organic frameworks (MOFs) incorporate nodes that are small metal oxide
clusters. Some of these MOFs are stable at high temperatures, offering good prospects as …

Abstract Embedding cubane [M4 (OH) 4](M= Ni, Co) clusters within the matrix of metal–
organic frameworks (MOFs) is a strategy to develop materials with unprecedented …

Ferritin, a distinctive iron-storage protein, possesses a unique cage-like nanoscale structure
that enables it to encapsulate and deliver a wide range of biomolecules. Recent advances …

Enantioselective C–H amidation offers attractive means to assemble C–N bonds to
synthesize high-added value, nitrogen-containing molecules. In recent decades …

Iron–sulfur clusters have been reported to catalyze various redox transformations, including
the multielectron reduction of CO2 to hydrocarbons. Herein, we report the design and …

Cobalt oxides are recognized as one of the most efficient earth-abundant catalysts for
challenging oxidation chemistry, with substrates ranging from water to organic compounds …

Metalloenzymes play critical roles in the environment by catalyzing redox reactions in
biogeochemical cycles. The elucidation of structure–function relationships in these …

A major challenge to the implementation of artificial photosynthesis (AP), in which fuels are
produced from abundant materials (water and carbon dioxide) in an electrochemical cell …

There has been growing interest in performing organocatalysis within a supramolecular
system as a means of controlling reaction reactivity and stereoselectivity. Here, a protein is …

The biotin–streptavidin technology has been extensively exploited to engineer artificial
metalloenzymes (ArMs) that catalyze a dozen different reactions. Despite its versatility, the …