Chemical diversity for tailoring negative thermal expansion

Q Li, K Lin, Z Liu, L Hu, Y Cao, J Chen… - Chemical Reviews, 2022 - ACS Publications
Negative thermal expansion (NTE), referring to the lattice contraction upon heating, has
been an attractive topic of solid-state chemistry and functional materials. The response of a …

Negative thermal expansion in functional materials: controllable thermal expansion by chemical modifications

J Chen, L Hu, J Deng, X Xing - Chemical Society Reviews, 2015 - pubs.rsc.org
Negative thermal expansion (NTE) is an intriguing physical property of solids, which is a
consequence of a complex interplay among the lattice, phonons, and electrons …

Optimizing hydrogen storage in MOFs through engineering of crystal morphology and control of crystal size

K Suresh, D Aulakh, J Purewal, DJ Siegel… - Journal of the …, 2021 - ACS Publications
Metal–organic frameworks (MOFs) are promising materials for hydrogen storage that fail to
achieve expected theoretical values of volumetric storage density due to poor powder …

Negative thermal expansion in framework structure materials

N Shi, Y Song, X Xing, J Chen - Coordination Chemistry Reviews, 2021 - Elsevier
Negative thermal expansion (NTE) is a counterintuitive physical phenomenon that the unit
cell volume of material usually contracts instead of expands upon heating. With two …

Negative Poisson's ratio in modern functional materials

C Huang, L Chen - Advanced Materials, 2016 - Wiley Online Library
Materials with negative Poisson's ratio attract considerable attention due to their underlying
intriguing physical properties and numerous promising applications, particularly in stringent …

Elucidation of flexible metal-organic frameworks: Research progresses and recent developments

JH Lee, S Jeoung, YG Chung, HR Moon - Coordination Chemistry Reviews, 2019 - Elsevier
Flexibility is a unique property of metal-organic frameworks (MOFs) that differentiates them
from other rigid inorganic porous materials such as zeolites and porous silica. Flexible …

Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques

S Bordiga, E Groppo, G Agostini… - Chemical …, 2013 - ACS Publications
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers

JP Zhang, PQ Liao, HL Zhou, RB Lin… - Chemical Society …, 2014 - pubs.rsc.org
X-Ray single-crystal diffraction has been the most straightforward and important technique in
structural determination of crystalline materials for understanding their structure–property …

PASCal: a principal axis strain calculator for thermal expansion and compressibility determination

MJ Cliffe, AL Goodwin - Journal of Applied Crystallography, 2012 - journals.iucr.org
This article describes a web-based tool (PASCal; principal axis strain calculator;
http://pascal. chem. ox. ac. uk) designed to simplify the determination of principal coefficients …

Negative thermal expansion and associated anomalous physical properties: review of the lattice dynamics theoretical foundation

MT Dove, H Fang - Reports on Progress in Physics, 2016 - iopscience.iop.org
Negative thermal expansion (NTE) is the phenomenon in which materials shrink rather than
expand on heating. Although NTE had been previously observed in a few simple materials …