Alkyne hydrosilylation is one of the most efficient methods for the synthesis of alkenyl silicon
derivatives and has been a hot topic of research for decades. This short review summarizes …

In view of the exciting advancement on silicon-carbon bond-forming transformations
achieved in the past decade, this review intends to show a unified illustration of the recent …

In the quest for designing efficient and stable photocatalytic materials for CO2 reduction,
hybridizing a selective noble-metal-free molecular catalyst and carbon-based light …

Single-atom site (SAS) catalysts have attracted considerable attention due to their excellent
performance. However, most of the current research models of SAS catalysts are based on …

To explore how to access bimetallic catalysts that can outperform their monometallic
analogues, a set of mono-and bimetallic NHC/phosphine (NHC= N-heterocyclic carbene) …

Electrocatalytic nitrite reduction (NO2RR) based on transition metal complexes is a
promising approach for the production of ammonia under mild conditions. Herein, we report …

In all previously reported metallacycloprop-1-ene or η2-vinyl complexes, the metal center
bears only one vinyl moiety. We have now successfully synthesized and structurally …

An electrochemical method for the decarboxylative silylation of α, β-unsaturated carboxylic
acids was developed. A variety of alkenylsilanes could be obtained in satisfactory yields and …

In the past few decades, chemistry of cyclometalated species has gained momentum with
increased applications in several areas of scientific developments. Cyclometalation …

Abstract Rh (I) NHC and Rh (III) Cp* NHC complexes (Cp*= pentamethylcyclopentadienyl,
NHC= N‐heterocyclic carbene= pyrid‐2‐ylimidazol‐2‐ylidene (Py− Im), thiophen‐2 …