Quantum chemistry calculations of technetium and rhenium compounds with application in radiopharmacy

D Hernández-Valdés, R Alberto, U Jáuregui-Haza - RSC advances, 2016 - pubs.rsc.org
In the last 15 years, computational quantum chemistry has become an invaluable tool that
supports the interpretation of experimental measurements of a broad range of molecular …

DNA interaction studies of rhenium compounds with Schiff base chelates encompassing biologically relevant moieties

MB Ismail, IN Booysen, MP Akerman - … , Nucleotides and Nucleic …, 2019 - Taylor & Francis
Herein, we report the DNA interaction studies of rhenium (I) and-(V) compounds with Schiff
base chelates encompassing biologically relevant moieties. More specifically, the DNA …

Substitution reactivity and structural variability induced by tryptamine on the biomimetic rhenium tricarbonyl complex

FJF Jacobs, GJS Venter, E Fourie, RE Kroon, A Brink - RSC advances, 2021 - pubs.rsc.org
A series of seven fac-[Re (CO) 3 (5Me-Sal-Trypt)(L)] complexes containing tryptamine on the
N, O 5-methyl-salicylidene bidentate ligand backbone and where L is MeOH, Py, Imi, DMAP …

Nuclearity manipulation in Schiff-base fac-tricarbonyl complexes of Mn (I) and Re (I)

PP Mokolokolo, A Frei, MS Tsosane, DV Kama… - Inorganica Chimica …, 2018 - Elsevier
A range of bidentate Schiff-base ligands, 2-(cyclohexyliminomethyl) phenol, 2-(cyclopentyl)
methyl-5-methylphenol and 5-methyl-2-(phenylethyliminimethyl) phenol, with a variation in …

Synthesis, structural elucidation, and catalytic activity of bimetallic rhenium-tin complexes containing Schiff base ligand

M Kaur, A Kapila, V Yempally, H Kaur - Journal of Molecular Structure, 2022 - Elsevier
Novel bimetallic systems with Re and Sn metals, containing Schiff base linker were
designed and explored for their cooperative effect in the catalysis. ReSn bimetallic …

Solid State Isostructural Behavior and Quantified Limiting Substitution Kinetics in Schiff-Base Bidentate Ligand Complexes fac-[Re(O,N-Bid)(CO)3(MeOH)]n

A Brink, HG Visser, A Roodt - Inorganic Chemistry, 2014 - ACS Publications
A range of N, O-donor atom salicylidene complexes of the type fac-[M (O, N-Bid)(CO) 3 (L)] n
(O, N-Bid= anionic N, O-bidentate ligands; L= neutral coordinated ligand) have been …

New approach for the synthesis of water soluble fac-[MI (CO) 3]+ bis (diarylphosphino) alkylamine complexes (M= 99 Tc, Re)

DV Kama, A Frei, A Brink, H Braband, R Alberto… - Dalton …, 2021 - pubs.rsc.org
A novel proof-of-concept is reported to modify the water solubility and potential biological
effects of a bis (diphenylphosphino) alkylamine (PNP) ligand and the corresponding metal …

Substituted bidentate and ancillary ligands modulate the bioimaging properties of the classical Re (i) tricarbonyl core with yeasts and bacteria

A Carreño, AE Aros, C Otero, R Polanco… - New Journal of …, 2017 - pubs.rsc.org
Rhenium (I) tricarbonyl complexes with heteroaromatic ligands have been intensely
investigated with respect to their properties as imaging probes, although they have only …

Self‐Assembled Multinuclear Complexes Incorporating 99mTc

A Frei, PP Mokolokolo, R Bolliger… - … A European Journal, 2018 - Wiley Online Library
Multinuclear complexes or clusters are rarely investigated in medicinal inorganic chemistry
although they represent structural intermediates between molecules and nanomaterials. We …

Ambient and high-pressure kinetic investigation of methanol substitution in fac-[Re (Trop)(CO) 3 (MeOH)] by different monodentate nucleophiles

M Schutte-Smith, A Roodt, HG Visser - Dalton Transactions, 2019 - pubs.rsc.org
Methanol substitution in the fac-[Re (CO) 3 (Trop)(MeOH)] complex (Trop−= tropolonate)
was studied with a range of seven nucleophiles, namely pyridine (Py), 4 …