Homogeneous Hydrogenation of CO2 and CO to Methanol: The Renaissance of Low‐Temperature Catalysis in the Context of the Methanol Economy

R Sen, A Goeppert… - Angewandte Chemie …, 2022 - Wiley Online Library
The traditional economy based on carbon‐intensive fuels and materials has led to an
exponential rise in anthropogenic CO2 emissions. Outpacing the natural carbon cycle …

Homogeneous catalysis for sustainable hydrogen storage in formic acid and alcohols

K Sordakis, C Tang, LK Vogt, H Junge… - Chemical …, 2018 - ACS Publications
Hydrogen gas is a storable form of chemical energy that could complement intermittent
renewable energy conversion. One of the main disadvantages of hydrogen gas arises from …

Manganese complexes for (de) hydrogenation catalysis: a comparison to cobalt and iron catalysts

F Kallmeier, R Kempe - Angewandte Chemie International …, 2018 - Wiley Online Library
The sustainable use of the resources on our planet is essential. Noble metals are very rare
and are diversely used in key technologies, such as catalysis. Manganese is the third most …

[HTML][HTML] Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers

FH Isikgor, CR Becer - Polymer chemistry, 2015 - pubs.rsc.org
The demand for petroleum dependent chemicals and materials has been increasing despite
the dwindling of their fossil resources. As the dead-end of petroleum based industry has …

Metal–ligand cooperation

JR Khusnutdinova, D Milstein - … Chemie International Edition, 2015 - Wiley Online Library
Metal–ligand cooperation (MLC) has become an important concept in catalysis by transition
metal complexes both in synthetic and biological systems. MLC implies that both the metal …

[HTML][HTML] Formic acid as a hydrogen storage material–development of homogeneous catalysts for selective hydrogen release

D Mellmann, P Sponholz, H Junge… - Chemical Society Reviews, 2016 - pubs.rsc.org
Formic acid (FA, HCO2H) receives considerable attention as a hydrogen storage material. In
this respect, hydrogenation of CO2 to FA and dehydrogenation of FA are crucial reaction …

Homogeneous transition metal catalysis of acceptorless dehydrogenative alcohol oxidation: applications in hydrogen storage and to heterocycle synthesis

RH Crabtree - Chemical Reviews, 2017 - ACS Publications
The different types of acceptorless alcohol dehydrogenation (AAD) reactions are discussed,
followed by the catalysts and mechanisms involved. Special emphasis is put on the common …

Hydrogenative depolymerization of nylons

A Kumar, N von Wolff, M Rauch, YQ Zou… - Journal of the …, 2020 - ACS Publications
The widespread crisis of plastic pollution demands discovery of new and sustainable
approaches to degrade robust plastics such as nylons. Using a green and sustainable …

Bond activation and catalysis by ruthenium pincer complexes

C Gunanathan, D Milstein - Chemical reviews, 2014 - ACS Publications
Activation of inert chemical bonds by transition metal complexes is an area of utmost
importance. Efficient bond activation can provide a leading entry to successful catalytic …

Hydroxide Based Integrated CO2 Capture from Air and Conversion to Methanol

R Sen, A Goeppert, S Kar… - Journal of the American …, 2020 - ACS Publications
The first example of an alkali hydroxide-based system for CO2 capture and conversion to
methanol has been established. Bicarbonate and formate salts were hydrogenated to …