Conspectus Recently, alkene dicarbofunctionalization, ie, the powerful organic synthesis
method of alkene difunctionalization with two carbon sources, emerged as a formidable …

The direct difunctionalization of alkenes, a cheap and abundant feedstock, represents one of
the most attractive strategies for increasing molecular complexity in synthetic organic …

Migration of metals along a carbon chain is triggered by two of the most common
organometallic elementary steps–β-hydride (β-H) elimination and alkene hydrometallation …

Abstract Transition‐metal catalyzed intermolecular 1, 2‐diarylation of electronically
unactivated alkenes has emerged as an extensive research topic in organic synthesis …

Herein, we disclose a Ni-catalyzed 1, 1-difunctionalization of unactivated terminal alkenes
that enables the incorporation of two different heteroatom motifs across an olefin backbone …

The asymmetric addition of an N–H bond to various alkenes via a direct catalytic method is a
powerful way of synthesizing value-added chiral amines. Therefore, the enantio-and …

Reported herein is a modular, NiH-catalyzed system capable of proximal-selective
hydroamination of unactivated alkenes with diverse amine sources. The key to the …

We disclose a Ni-catalyzed vicinal difunctionalization of alkenes with benzyl halides and
alkylzinc reagents, which produces products with two new alkyl–alkyl bonds. This alkene …

Abstract A catalytic 1, 1‐difunctionalization of unactivated olefins en route to sp3 bis‐
organometallic B, B (Si)‐reagents is described. The protocol is characterized by exceptional …

An enantioselective addition reaction of various alkyl groups to unactivated internal alkenes
under Cu catalysis has been developed. The reaction uses amide-linked aminoquinoline as …