Catalytic applications of vanadium: a mechanistic perspective

RR Langeslay, DM Kaphan, CL Marshall… - Chemical …, 2018 - ACS Publications
The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present
review, reactions catalyzed by homogeneous and supported vanadium complexes from …

Development of halogenase enzymes for use in synthesis

J Latham, E Brandenburger, SA Shepherd… - Chemical …, 2018 - ACS Publications
Nature has evolved halogenase enzymes to regioselectively halogenate a diverse range of
biosynthetic precursors, with the halogens introduced often having a profound effect on the …

Binding of vanadium ions and complexes to proteins and enzymes in aqueous solution

JC Pessoa, MFA Santos, I Correia, D Sanna… - Coordination Chemistry …, 2021 - Elsevier
The understanding of the role of vanadium enzymes and of vanadium compounds (VCs) in
biology, as well as the design of new vanadium-based species for catalysis, materials …

Vanadium and proteins: Uptake, transport, structure, activity and function

JC Pessoa, E Garribba, MFA Santos… - Coordination chemistry …, 2015 - Elsevier
Vanadium is an element ubiquitously present in our planet's crust and thus there are several
organisms that use vanadium for activity or function of proteins. Examples are the vanadium …

Recent development of biomimetic halogenation inspired by vanadium dependent haloperoxidase

Z Chen - Coordination Chemistry Reviews, 2022 - Elsevier
Organohalide is one of the most important and useful compounds in organic chemistry,
broadly embodied in diverse bioactive molecules, organic materials and agrochemicals …

Binary and ternary vanadium oxides: general overview, physical properties, and photochemical processes for environmental applications

O Monfort, P Petrisková - Processes, 2021 - mdpi.com
This review article is a comprehensive report on vanadium oxides which are interesting
materials for environmental applications. Therefore, a general overview of vanadium and its …

Vanadium–phosphatase complexes: Phosphatase inhibitors favor the trigonal bipyramidal transition state geometries

CC McLauchlan, BJ Peters, GR Willsky… - Coordination Chemistry …, 2015 - Elsevier
Over the past two decades increasing information about the function and structural detail of
phosphatases has become available detailing the interaction with vanadate or other …

Vanadium haloperoxidases: From the discovery 30 years ago to X-ray crystallographic and V K-edge absorption spectroscopic studies

C Leblanc, H Vilter, JB Fournier, L Delage… - Coordination Chemistry …, 2015 - Elsevier
In the environment, vanadium-dependent haloperoxidases (VHPO) are likely to play a key
role in the production of biogenic organohalogens. These enzymes contain vanadate as a …

Functional enzyme mimics for oxidative halogenation reactions that combat biofilm formation

K Herget, H Frerichs, F Pfitzner, MN Tahir… - … : Connecting Biology and …, 2020 - Springer
Chemical halogenation is an important transformation in organic synthesis. Halogenations
involve the use of reactive and toxic halogens (X 2) or hydrogen halides (HX). Chemical …

Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid

S Song, X Li, X Sun, Y Yuan, N Jiao - Green Chemistry, 2015 - pubs.rsc.org
The oxidative bromination of olefins, alkynes, and ketones has been developed with HBr as
the brominating reagent and DMSO as the mild oxidant. The simple conditions, high …