Catalytic applications of vanadium: a mechanistic perspective
RR Langeslay, DM Kaphan, CL Marshall… - Chemical …, 2018 - ACS Publications
The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present
review, reactions catalyzed by homogeneous and supported vanadium complexes from …
review, reactions catalyzed by homogeneous and supported vanadium complexes from …
Development of halogenase enzymes for use in synthesis
J Latham, E Brandenburger, SA Shepherd… - Chemical …, 2018 - ACS Publications
Nature has evolved halogenase enzymes to regioselectively halogenate a diverse range of
biosynthetic precursors, with the halogens introduced often having a profound effect on the …
biosynthetic precursors, with the halogens introduced often having a profound effect on the …
Binding of vanadium ions and complexes to proteins and enzymes in aqueous solution
The understanding of the role of vanadium enzymes and of vanadium compounds (VCs) in
biology, as well as the design of new vanadium-based species for catalysis, materials …
biology, as well as the design of new vanadium-based species for catalysis, materials …
Vanadium and proteins: Uptake, transport, structure, activity and function
Vanadium is an element ubiquitously present in our planet's crust and thus there are several
organisms that use vanadium for activity or function of proteins. Examples are the vanadium …
organisms that use vanadium for activity or function of proteins. Examples are the vanadium …
Recent development of biomimetic halogenation inspired by vanadium dependent haloperoxidase
Z Chen - Coordination Chemistry Reviews, 2022 - Elsevier
Organohalide is one of the most important and useful compounds in organic chemistry,
broadly embodied in diverse bioactive molecules, organic materials and agrochemicals …
broadly embodied in diverse bioactive molecules, organic materials and agrochemicals …
Binary and ternary vanadium oxides: general overview, physical properties, and photochemical processes for environmental applications
O Monfort, P Petrisková - Processes, 2021 - mdpi.com
This review article is a comprehensive report on vanadium oxides which are interesting
materials for environmental applications. Therefore, a general overview of vanadium and its …
materials for environmental applications. Therefore, a general overview of vanadium and its …
Vanadium–phosphatase complexes: Phosphatase inhibitors favor the trigonal bipyramidal transition state geometries
CC McLauchlan, BJ Peters, GR Willsky… - Coordination Chemistry …, 2015 - Elsevier
Over the past two decades increasing information about the function and structural detail of
phosphatases has become available detailing the interaction with vanadate or other …
phosphatases has become available detailing the interaction with vanadate or other …
Vanadium haloperoxidases: From the discovery 30 years ago to X-ray crystallographic and V K-edge absorption spectroscopic studies
C Leblanc, H Vilter, JB Fournier, L Delage… - Coordination Chemistry …, 2015 - Elsevier
In the environment, vanadium-dependent haloperoxidases (VHPO) are likely to play a key
role in the production of biogenic organohalogens. These enzymes contain vanadate as a …
role in the production of biogenic organohalogens. These enzymes contain vanadate as a …
Functional enzyme mimics for oxidative halogenation reactions that combat biofilm formation
K Herget, H Frerichs, F Pfitzner, MN Tahir… - … : Connecting Biology and …, 2020 - Springer
Chemical halogenation is an important transformation in organic synthesis. Halogenations
involve the use of reactive and toxic halogens (X 2) or hydrogen halides (HX). Chemical …
involve the use of reactive and toxic halogens (X 2) or hydrogen halides (HX). Chemical …
Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid
The oxidative bromination of olefins, alkynes, and ketones has been developed with HBr as
the brominating reagent and DMSO as the mild oxidant. The simple conditions, high …
the brominating reagent and DMSO as the mild oxidant. The simple conditions, high …