Air‐Stable Organic Radicals: New‐Generation Materials for Flexible Electronics?

L Ji, J Shi, J Wei, T Yu, W Huang - Advanced Materials, 2020 - Wiley Online Library
In the last few years, air‐stable organic radicals and radical polymers have attracted
tremendous attention due to their outstanding performance in flexible electronic devices …

Carbon-based Biradicals: Structural and Magnetic Switching

Y Ishigaki, T Harimoto, T Shimajiri, T Suzuki - Chemical Reviews, 2023 - ACS Publications
Sterically hindered C═ C double bonds often deform into a bent or twisted geometry. Thus,
many overcrowded ethylenes or anthraquinodimethanes can adopt multiple conformations …

Platforms for stable carbon‐centered radicals

K Kato, A Osuka - Angewandte Chemie International Edition, 2019 - Wiley Online Library
Organic radicals can potentially play important roles in functional materials owing to an
unpaired electron, but they are usually highly reactive and difficult to use. Therefore …

Synthesis of π-Extended Thiele's and Chichibabin's Hydrocarbons and Effect of the π-Congestion on Conformations and Electronic States

T Nishiuchi, S Aibara, H Sato… - Journal of the American …, 2022 - ACS Publications
The biradicaloid of Chichibabin's hydrocarbon exits in a unique thermal equilibrium between
closed-shell singlet and open-shell triplet forms. Conceptually, the incorporation of …

Electro-optical π-radicals: design advances, applications and future perspectives

P Murto, H Bronstein - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The unique open-shell electronic structure of neutral π-radicals has inspired research on
novel molecular materials for over a century. In recent years, rapid development in carbon …

Sulfone-Functionalized Chichibabin's Hydrocarbons: Stable Diradicaloids with Symmetry Breaking Charge Transfer Contributing to NIR Emission beyond 900 nm

Z Zhou, K Yang, L He, W Wang, W Lai… - Journal of the …, 2024 - ACS Publications
While monoradical emitters have emerged as a new route toward efficient organic light-
emitting diodes, the luminescence property of organic diradicaloids is still scarcely explored …

[HTML][HTML] Efficient light-emitting diodes from organic radicals with doublet emission

JM Hudson, TJH Hele, EW Evans - Journal of Applied Physics, 2021 - pubs.aip.org
Organic light-emitting diodes (OLEDs) with doublet-spin radical emitters have emerged as a
new route to efficient display technologies. In contrast to standard organic semiconductors …

Photoinduced multi-color emission of naphthalenediimide radical in different solvents and dynamic anti-counterfeiting film

YS Shi, DD Yang, T Xiao, ZG Xia, YH Fang… - Chemical Engineering …, 2023 - Elsevier
Developing innovative materials with environmentally stable 1, 4, 5, 8-Naphthalene diimide
radicals (NDI radical dot−) emissions is significant. In this work, we have successfully …

Bottom‐Up Construction of Fluorene‐Based Porous Aromatic Frameworks for Ultrahigh‐Capacity and High‐Rate Alkali Metal‐Ion Batteries

S Zhao, Z Bian, Z Liu, Y Wang, F Cui… - Advanced Functional …, 2022 - Wiley Online Library
Porous aromatic frameworks (PAFs) have attracted much attention in various fields, yet an
understanding of their applications in energy storage systems is in its infancy. Herein, a …

Recent progress in open-shell organic conjugated materials and their aggregated states

S Dong, Z Li - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
In the last few decades, open-shell organic materials have attracted great attention from
scientists due to their new chemical and physical properties, as well as their possible …