Manganese (iii) acetate in organic synthesis: a review of the past decade

J Wang, Y Zhang, Y Zhou, X Gu, B Han… - Organic Chemistry …, 2024 - pubs.rsc.org
Mn (OAc) 3 has emerged as a highly valuable one-electron oxidant in the fields of synthetic
and medicinal chemistry, owing to its mild reactivity, economic feasibility, and low toxicity. In …

Recent Advances and Prospects in Manganese‐Catalyzed C− H Activation

G Anusree, PS Devi, G Anilkumar - Advanced Synthesis & …, 2024 - Wiley Online Library
C− H activation represents an interesting alternative to conventional cross‐coupling
methods, avoiding the requirement of additional steps to introduce activating groups …

Lewis acid-catalyzed chemodivergent and regiospecific reaction of phenols with quaternary peroxyoxindoles

MA Shaikh, PP Samal, AS Ubale… - The Journal of …, 2022 - ACS Publications
The indium-catalyzed regiospecific coupling of substituted phenol derivatives and
quaternary peroxyoxindoles for the synthesis of C2 or C4 benzoxazin-3-one-substituted …

FeCl2-Mediated Rearrangement of Aminoperoxides into Functionalized Tetrahydrofurans: Dynamic Non-innocence of O-Ligands at an Fe Center Coordinates a …

YY Belyakova, PS Radulov, RA Novikov… - Journal of the …, 2024 - ACS Publications
The selective reaction of cyclic aminoperoxides with FeCl2 proceeds through a sequence of
O–O and C–C bond cleavages, followed by intramolecular cyclization, yielding …

A Mn-catalyzed remote C (sp 3)–H bond peroxidation triggered by radical trifluoromethylation of unactivated alkenes

L Wang, Y Ma, Y Jiang, L Lv, Z Li - Chemical Communications, 2021 - pubs.rsc.org
A manganese-catalyzed radical relay strategy for the remote trifluoromethylation–
peroxidation of unactivated alkenes is disclosed. The electrophilic CF3 group was added to …

t-BuOOH/TiO2 Photocatalytic System as a Convenient Peroxyl Radical Source at Room Temperature under Visible Light and Its Application for the CH-Peroxidation …

ER Lopat'eva, IB Krylov, AO Terent'ev - Catalysts, 2023 - mdpi.com
TiO2 is one of the most promising heterogeneous photoredox catalysts employed in
oxidative pollutant destruction, CO2 reduction, water splitting, disinfection, solar cell design …

Peroxidation and Skeletal Rearrangement for the Synthesis of Dioxole‐2‐Carboxamide Derivatives under Continuous‐Flow Conditions

AS Ubale, MA Shaikh, N Mohanta… - Advanced Synthesis …, 2023 - Wiley Online Library
Herein, we report peroxidative dearomatization of 2‐naphthol and C− H peroxidation of 3‐
arylbenzofuran‐2‐ones with 66–94% yield under catalyst‐free conditions using continuous …

Sequential Oxidative Fragmentation and Skeletal Rearrangement of Peroxides for the Synthesis of Quinazolinone Derivatives

AS Ubale, MA Shaikh… - The Journal of Organic …, 2021 - ACS Publications
For the first time, the sequential reaction of peroxyoxindole that involves base-promoted
oxidative fragmentation to isocyanate formation and primary amine or amino alcohol …

Bioinspired Fe (II)‐Mediated Halogenative C− C Bond Activation of Ozonides: Temporary Installment of a Peroxide Bridge Allows Selective C− C Scissions for …

IA Yaremenko, YY Belyakova… - Advanced Synthesis …, 2023 - Wiley Online Library
A selective reaction of bridged ozonides with Fe (II) salts proceeds through the sequence of
O− O, C− C scissions and halogenation to form α‐halogen substituted δ‐ketoesters and δ …

Advances in radical peroxidation with hydroperoxides

OV Bityukov, PY Serdyuchenko… - Beilstein Journal of …, 2024 - beilstein-journals.org
Organic peroxides have become sought-after functionalities, particularly following the multi-
tone consumption in polymer production and success in medicinal chemistry. The selective …