Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Role of the support in gold-containing nanoparticles as heterogeneous catalysts

M Sankar, Q He, RV Engel, MA Sainna… - Chemical …, 2020 - ACS Publications
In this review, we discuss selected examples from recent literature on the role of the support
on directing the nanostructures of Au-based monometallic and bimetallic nanoparticles. The …

Metal organic frameworks as versatile hosts of Au nanoparticles in heterogeneous catalysis

A Dhakshinamoorthy, AM Asiri, H Garcia - ACS Catalysis, 2017 - ACS Publications
The present review describes the state of the art of the use of metal organic framework
(MOF)-encapsulated Au nanoparticles (NPs) as heterogeneous catalysts. The purpose is to …

Selective Catalytic Oxidation of C H Bonds with Molecular Oxygen

E Roduner, W Kaim, B Sarkar, VB Urlacher… - …, 2013 - Wiley Online Library
Although catalytic reductions, cross‐couplings, metathesis, and oxidation of C C double
bonds are well established, the corresponding catalytic hydroxylations of C H bonds in …

[HTML][HTML] Supported gold nanoparticles as catalysts for the oxidation of alcohols and alkanes

SAC Carabineiro - Frontiers in Chemistry, 2019 - frontiersin.org
Supporting gold nanoparticles have shown to be extremely active for many industrially
important reactions, including oxidations. Two representative examples are the oxidation of …

Heterogeneous catalysis by gold

T Takei, T Akita, I Nakamura, T Fujitani, M Okumura… - Advances in …, 2012 - Elsevier
Gold can be deposited as nanoparticles (NPs) with diameters of 2–5 nm and clusters with
diameters less than 2 nm on a variety of materials such as oxides, carbides, and sulfides of …

Hybrid mesoporous silica/noble-metal nanoparticle materials—synthesis and catalytic applications

M Davidson, Y Ji, GJ Leong, NC Kovach… - ACS Applied Nano …, 2018 - ACS Publications
Due to the uniform and stable pore structure, mesoporous silica has attracted increasing
research attention as a catalyst support material. As a large family of mesoporous silica …

Selective oxidation of saturated hydrocarbons using Au–Pd alloy nanoparticles supported on metal–organic frameworks

J Long, H Liu, S Wu, S Liao, Y Li - Acs Catalysis, 2013 - ACS Publications
Gold (Au) and palladium (Pd) nanoparticles dispersed on a zeolite-type metal–organic
framework (ie, MIL-101) were prepared via a simple colloidal method. The catalysts were …

Selective liquid phase oxidation with supported metal nanoparticles

N Dimitratos, JA Lopez-Sanchez, GJ Hutchings - Chemical Science, 2012 - pubs.rsc.org
Over the past twenty years there has been intense interest in the design and understanding
of catalysis by gold. More recently, it has been observed that alloying gold with a second …

Metal–organic frameworks as catalysts for oxidation reactions

A Dhakshinamoorthy, AM Asiri… - Chemistry–A European …, 2016 - Wiley Online Library
This Concept is aimed at describing the current state of the art in metal–organic frameworks
(MOFs) as heterogeneous catalysts for liquid‐phase oxidations, focusing on three important …