Synthesis of Chiral Graphene Structure and its Comprehensive Applications: A Critical Review

A Sinha, H So - Nanoscale Horizons, 2024 - pubs.rsc.org
From a molecular viewpoint, chirality is a crucial factor in biological processes. Enantiomers
of a molecule have identical chemical and physical properties, but chiral molecules found in …

Functionalized Cycloolefin Ligand as a Solution to Ortho-Constraint in the Catellani-Type Reaction

FY Wang, YX Li, L Jiao - Journal of the American Chemical …, 2023 - ACS Publications
The Catellani reaction, ie, the Pd/norbornene (NBE) catalysis, has been evolved into a
versatile approach to multisubstituted arenes via the ortho-functionalization/ipso-termination …

Palladium-Catalyzed [3 + 2] Annulation of ortho-Substituted Iodoarenes with Maleimides via a Consecutive Double Heck-type Strategy

J Naveen, G Satyanarayana - The Journal of Organic Chemistry, 2023 - ACS Publications
Herein, we report an efficient [3+ 2] annulation of ortho-substituted iodoarenes with
maleimides via a palladium-catalyzed consecutive double Heck-type strategy, leading to …

Ortho C–H Bond Activations in an Atmospheric Microwave Plasma Ion Source

G Chen, F Chu, S Zhang, W Li, S Zhou… - Journal of the …, 2024 - ACS Publications
C–H bond ortho-substitution reaction has always been a significant and challenging topic in
organic chemistry. We proposed a synthesis method based on microwave plasma torches …

Carboamination and olefination: ortho C–H functionalization of phenoxyacetamide

T Nanda, SK Dhal, GKD Adhikari, N Prusty… - Chemical …, 2023 - pubs.rsc.org
Herein, we have demonstrated a rhodium-catalyzed carboamination of olefin with the
double bond intact. For the first time, deacylative carboamination of the maleimide has been …

Theoretical insights into Rh-catalyzed hydroamidation: Mechanism and chemoselectivity

J Wang, Z Zheng, K Zheng, Q Jiang, Y Hu - Molecular Catalysis, 2024 - Elsevier
Rh-catalyzed hydroamidation of unactivated alkenes were investigated by a density
functional theory study. The catalytic cycle proceeds through β-H elimination, alkene …