Homogeneous gold catalysis has experienced extraordinary development since the dawn of
this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the …

Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Presented herein is the first report of enantioselective Au (I)/Au (III) redox catalysis, enabled
by a newly designed hemilabile chiral (P, N)-ligand (ChetPhos). The potential of this concept …

Interest in homogeneous gold catalysis has undergone a marked increase. As strong yet air-
and moisture-tolerant π-acids, cationic gold (I) complexes have been shown to catalyze …

Bimetallic catalysis represents an alternative paradigm for coupling chemistry that
complements the more traditional single-site catalysis approach. In this perspective, recent …

Alkene aminoarylation with a single, bifunctional reagent is a concise synthetic strategy. We
report a catalytic protocol for the addition of arylsulfonylacetamides across electron-rich …

Gold chemistry has developed extensively in the past decade, and a dozen good reviews
have been presented discussing this progress. Few however have paid close attention to …

A combination of visible light photocatalysis and gold catalysis is applied to a ring expansion–
oxidative arylation reaction. The reaction provides an entry into functionalized cyclic ketones …

Gold redox chemistry holds the promise of unique reactivities and selectivities that are
different to other transition metals. Recent studies have utilized strain release, ligand design …