Chemo-and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

EP Talsi, KP Bryliakov - Coordination Chemistry Reviews, 2012 - Elsevier
The discovery of simple and efficient catalyst systems for the selective oxofunctionalization
of hydrocarbons is a challenging task of modern chemistry. The biomimetic approach, which …

Microwave-assisted organic synthesis: General considerations and transformations of heterocyclic compounds

K Kranjc, M Kocevar - Current Organic Chemistry, 2010 - ingentaconnect.com
In this review paper we present the most important features of microwave irradiation, their
physical characteristics and the properties upon an interaction with matter. The heating …

Molecular iron complexes as catalysts for selective C–H bond oxygenation reactions

AC Lindhorst, S Haslinger, FE Kühn - Chemical Communications, 2015 - pubs.rsc.org
The selective oxygenation of C–H bonds is a promising and interesting task for both
academia and chemical industry. Inspired by the efficiency and selectivity of naturally …

Effective treatment of hospital wastewater with high-concentration diclofenac and ibuprofen using a promising technology based on degradation reaction catalyzed by …

Y Vieira, HA Pereira, J Leichtweis, CM Mistura… - Science of The Total …, 2021 - Elsevier
Real hospital wastewater was effectively treated by a promising technology based on
degradation reaction catalyzed by Fe 0 under microwave irradiation in this work. Fe 0 …

Highly Enantioselective C−H Oxidation of Arylalkanes with H2O2 in the Presence of Chiral Mn‐Aminopyridine Complexes

EP Talsi, DG Samsonenko, RV Ottenbacher… - …, 2017 - Wiley Online Library
Bioinspired chiral Mn‐aminopyridine complexes [(S, S)‐LMnII (OTf) 2] and [(R, R)‐LMnII
(OTf) 2](where (S, S)‐L=(2S, 2′ S)‐1, 1′‐bis ((3‐methyl‐4‐(2, 2, 2‐trifluoroethoxy) pyridin …

Metal-free and iron (II)-assisted oxidation of cyclohexane to adipic acid with ozone: A theoretical mechanistic study

ML Kuznetsov, AJL Pombeiro - Journal of Catalysis, 2021 - Elsevier
Adipic acid has a tremendous applied importance. Its industrial synthesis requires harsh
conditions and application/emission of hazardous HNO 3 and N 2 O. Here, a mechanism of …

Tuning Cyclohexane Oxidation: Combination of Microwave Irradiation and Ionic Liquid with the C-Scorpionate [FeCl2(Tpm)] Catalyst

APC Ribeiro, LM Martins, ML Kuznetsov… - …, 2017 - ACS Publications
For the first time, microwave (MW) irradiation was successfully applied to peroxidative
cyclohexane oxidation catalyzed by a C-scorpionate complex,[FeCl2 (Tpm)](1; Tpm …

Tetradentate Schiff base ligands and their complexes: synthesis, structural characterization, thermal, electrochemical and alkane oxidation

G Ceyhan, M Köse, V McKee, S Uruş, A Gölcü… - … Acta Part A: Molecular …, 2012 - Elsevier
Three Schiff base ligands (H2L1–H2L3) with N2O2 donor sites were synthesized by
condensation of 1, 5-diaminonapthalene with benzaldehyde derivatives. A series of Cu (II) …

Synthesis and catalytic activities of silica-supported multifunctional azo-containing schiff base complexes with Cu (II), Co (II), Ni (II) and Mn (II)

S Uruş, M Dolaz, M Tümer - Journal of Inorganic and Organometallic …, 2010 - Springer
Abstract A novel 4-((5-formyl-2, 4-dihydroxyphenyl) diazenyl) benzylphosphonic acid
(FPABP) ligand was synthesized and bound to silica-gel which was activated with 3 …

Copper (II) tetrazolato complexes: Role in oxidation catalysis and protein binding

M Saha, KM Vyas, LM Martins, NMR Martins… - Polyhedron, 2017 - Elsevier
Three new coordination complexes [Cu 2 (phen) 2 (ptz) 4](1),[Cu (phen)(pmtz) 2](2) and [Cu
(phen)(pytz) 2](3)(ptz= 5-phenyltetrazolate, pmtz= 5-(2-pyrimidyl) tetrazolate and pytz= 5-(2 …