Recent advances in hybrid materials of metal nanoparticles and polyoxometalates

K Xia, K Yamaguchi, K Suzuki - … Chemie International Edition, 2023 - Wiley Online Library
Abstract Polyoxometalates (POMs), anionic metal‐oxygen nanoclusters that possess various
composition‐dependent properties, are widely used to modify the existing properties of …

Hydrogenolysis of Lignin Model Compounds on Ni Nanoparticles Surrounding the Oxygen Vacancy of CeO2

J Xie, Y Xi, W Gao, H Zhang, Y Wu, R Zhang… - ACS …, 2023 - ACS Publications
The cleavage of C–O bonds presents the crucial step for realizing the depolymerization of
lignin. Herein, we report that Ni nanoparticles (NiNPs) supported on CeO2 with oxygen …

Photocatalytic transfer hydrogenolysis of aryl ethers

Z Peng, Z Wu, X Sun, H Li - Green Chemistry, 2023 - pubs.rsc.org
Aryl ethers greatly influence lignin depolymerization and the oxygen content in lignin
products. Cleaving aryl ethers normally requires harsh conditions such as high-pressure …

Partial hydrogenation of anisole to cyclohexanone in water medium catalyzed by atomically dispersed Pd anchored in the micropores of zeolite

K Xu, Y Chen, H Yang, Y Gan, L Wu, L Tan… - Applied Catalysis B …, 2024 - Elsevier
Cyclohexanone is an important raw material for manufacturing nylon and other chemicals.
The sustainable conversion of biomass derived molecules to cyclohexanone is desired but …

Two 3D Two-Fold Interpenetrated Dia-Like Polyoxometalate-Based Metal–Organic Frameworks: Synthesis and Sulfide Selective Oxidation Activity

X Bai, X Han, Y Wang, A Zhang, Y Yang, Y Lu… - Inorganic …, 2023 - ACS Publications
Two new three-dimensional (3D) polyoxometalate-based metal–organic frameworks
(POMOFs),[M2 (btap) 4 (H2O) 4 (HPMo10VI Mo2VO40)](M= Co (1) and Cd (2); btap= 3, 5 …

Selective hydrogenolysis of CO bonds in lignin and its model compounds over a high-performance Ru/AC catalyst under mild conditions

W Jiang, JP Cao, C Zhu, JX Xie, L Zhao… - Chemical Engineering …, 2022 - Elsevier
Selective hydrogenolysis of CO bonds in lignin is regarded as the most promising strategy to
produce high value-added biofuels and chemicals. Herein, Ru/AC catalysts of Ru supported …

A hydrophobic deep eutectic solvents-based integrated method for efficient and green extraction and recovery of natural products from Rosmarinus officinalis leaves …

T Wang, Q Wang, Q Guo, P Li, H Yang - Food Chemistry, 2021 - Elsevier
Green extraction and separation of natural products is crucial for food industry, and has
been widely concerned. Compared with hydrophilic natural products, the green extraction …

NHC–palladium-catalyzed ionic liquid-accelerated regioselective oxyarylation of alkynes with diaryl ethers

J Li, D He, Z Lin, L Cen, W Wu, H Jiang - Green Chemistry, 2022 - pubs.rsc.org
The first NHC–palladium-catalyzed regioselective oxyarylation of oxime ether in a task-
specific ionic liquid via C (sp3)–O and C (sp2)–O bond cleavage of two different types of …

Polyoxometalate as an Effective Catalyst for Catalytic Lignin into Value‐Added Molecules

H Zhang, S Fu - ChemCatChem, 2024 - Wiley Online Library
Lignin, an inherently heterogeneous arylpropanoid polymer, presents a unique resource for
the sustainable manufacture of aromatic chemicals and fuels. Recently, numerous catalytic …

Efficient hydrogenolysis of lignin model compounds and lignin by Ni-M/C and NaOH synergistic catalysis

X Li, H Wang, K Alorku, J Wang, L Ma, Y Xu - Fuel, 2024 - Elsevier
Efficient hydrogenolysis of CO bonds in lignin offers a promising pathway for producing high-
value-added biofuels and chemicals. However, designing an easily synthesized, highly …