The quest for alternatives to cyclopentadienyl-based ligands has led to a recent renaissance
of N-centered donor ligands in various fields of organometallic and coordination chemistry …

Methods and compositions for depositing rare earth metal containing layers are described
herein. In general, the dis closed methods deposit the precursor compounds comprising rare …

Published data on the coordination compounds of group 5 metals with diimine type ligands
are surveyed. Methods of synthesis, structural types, reactivity and properties of these …

Applications of inorganic thin films in the electronics industry have spurred activity in the
area of chemical vapor deposition (CVD). This article discusses the increasingly …

A series of structurally characterized new examples of pentacoordinated heteroleptic
tungsten (VI)− guanidinates complexes are described. Starting out from [WCl2 (N t-Bu) …

Four new tantalum amido precursors (η2-RN (CH2) n NR) Ta (NMe2) 3 (where R= Me, n= 2,
1; R= Et, n= 2, 2; R= Me, n= 3, 3; R= Et, n= 3, 4) with chelate diamide ligands and one new …

The activity of several imido vanadium complexes as catalysts of the guanylation reaction
was studied. Complex V (N-2, 6-iPr2C6H3) Cl3, 1, was found to be an efficient precatalyst …

The application of new zirconium precursors for the fabrication of ZrO2 and ZrN thin films by
metalorganic chemical vapor deposition (MOCVD) is presented. The all-nitrogen …

The application of two novel metalorganic complexes, namely the isostructural tris (N, N'-
diisopropyl-2-dimethlyamido-guanidinato) gadolinium (III)(1) and tris (N, N'-diisopropyl-2 …

Novel guanidinato complexes of hafnium [Hf {η2-(iPrN) 2CNR2} 2 (NR2) 2](R2= Et2, 1; Et,
Me, 2; Me2, 3), synthesized by insertion reactions of N, N '-diisopropylcarbodiimide into the …